Ecological assessment and forecasting of surface water conditions in the Dnipro river in Zaporizhzhia

  • L.A. Horoshkovа National university of Kyiv Mohyla academy, 2, Skovorody Str., Kyiv, 04070, Ukraine https://orcid.org/0000-0002-7142-4308
  • O. I. Menshov Taras Shevchenko National University of Kyiv, 60, Volodymyrska Str., Kyiv, 01033, Ukraine https://orcid.org/0000-0001-7280-8453
  • Y. D. Korniichuk National university of KyivMohyla academy, 2, Skovorody Str., Kyiv, 04070, Ukraine https://orcid.org/0009-0008-0742-3213
  • S. V. Horoshkov 1Taras Shevchenko National University of Kyiv, 60, Volodymyrska Str., Kyiv, 01033, Ukraine 2V.N. Karazin Kharkiv National University, 4, Svobody Sq., Kharkiv, 61022, Ukraine https://orcid.org/0009-0009-4310-9165
  • D. V. Maslov National university of Kyiv Mohyla academy, 2, Skovorody Str., Kyiv, 04070, Ukraine https://orcid.org/0009-0009-7397-8329
Keywords: Dnipro River, war consequences, surface water, ecological monitoring, phosphate, ammonium, sulfate, chloride, dissolved oxygen, BOD₅, anthropogenic impact, forecasting

Abstract

Purpose. To provide a comprehensive environmental assessment and forecast of the condition of surface waters of the Dnipro River within the Zaporizhzhia region, with a focus on the dynamics of key water quality indicators during the period 2013–2024. Special attention is given to anthropogenic factors, particularly the consequences of military actions and the destruction of the Kakhovka Hydroelectric Power Plant, which significantly altered the hydrological regime and impacted the ecological balance of the river.

Methods. Systems analysis, statistical data processing methods, distribution analysis, and regression modeling were employed to assess retrospective dynamics and predict future trends.

Results. Long-term monitoring data obtained from the Water Monitoring Laboratory of the Basin Water Resources Department of the Azov Sea Rivers were used. The primary focus was on evaluating six key water quality indicators: phosphates, ammonium, sulfate and chloride ions, biochemical oxygen demand over five days (BOD₅), and dissolved oxygen concentration, to assess the ecological state of the Dnipro River's surface waters in the Zaporizhzhia region, particularly in the drinking water intake area (DVS No. 1) in the upper reservoir of the Dnipro HPP. Phosphate and ammonium concentrations show periodic fluctuations driven by seasonal factors and fertilizer usage. Sulfate levels exhibit high variability of both natural and anthropogenic origin, while chloride concentrations remain relatively stable. Data on dissolved oxygen and BOD₅ indicate seasonal dynamics, which have been disrupted since 2023 due to the destruction of the Kakhovka Dam. The analysis confirmed the river's capacity for partial self-recovery, particularly under reduced anthropogenic pressure during wartime. Regression models were developed for predictive assessment of pollution levels and environmental risks.

Conclusions. The study identified key ecological problems in the Dnipro River, including organic and mineral pollution, disrupted hydrological regimes, and decreased oxygenation. The war-related destruction of hydrotechnical infrastructure exacerbated these issues. Despite this, the river demonstrated resilience through natural self-purification processes, especially as phosphate and ammonium loads declined. Restoration of ecological balance will require systemic monitoring, rehabilitation of water infrastructure, and regulation of pollutant sources. The developed models provide a basis for forecasting and managing surface water quality under both peacetime and post-war recovery scenarios.

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Author Biographies

L.A. Horoshkovа, National university of Kyiv Mohyla academy, 2, Skovorody Str., Kyiv, 04070, Ukraine

DSc (Economy), Professor, Professor of the Department of Ecology

O. I. Menshov , Taras Shevchenko National University of Kyiv, 60, Volodymyrska Str., Kyiv, 01033, Ukraine

DSc (Geology), Senior Researcher, Department of Geoinformatics

Y. D. Korniichuk, National university of KyivMohyla academy, 2, Skovorody Str., Kyiv, 04070, Ukraine

Bachelor,

 

S. V. Horoshkov, 1Taras Shevchenko National University of Kyiv, 60, Volodymyrska Str., Kyiv, 01033, Ukraine 2V.N. Karazin Kharkiv National University, 4, Svobody Sq., Kharkiv, 61022, Ukraine

Bachelor,

 

 

D. V. Maslov, National university of Kyiv Mohyla academy, 2, Skovorody Str., Kyiv, 04070, Ukraine

Postgraduate Student

 

References

Savchuk, D. (2003). Ecological and economic aspects of the functioning of the Dnipro reser-voirs. Ecological Bulletin, (5–6), 24–26. (in Ukrainian)

Ponomarenko, R.V., Pliatsuk, L.D., Tretyakov, O.V., & Kovaliov, P.A. (2019)/ Determination of the eco-logical state of Ukraine's main water supply source. Technogenic and Ecological Safety, 6(2/2019), 69–77. Retrieved from http://jteb.nuczu.edu.ua/en/2-text/122-determination-of-the-ecological-state-of-the-main-source-of-water-supply-of-ukraine (in Ukrainian)

Bezsonnyi, V., Tretyakov, O., Khalmuradov, B., & Ponomarenko, R. (2017). Examining the dynamics and modeling of oxygen regime of Chervonooskil water reservoir. Eastern-European Journal of Enter-prise Technologies, 5/10(89), 32–38. Retrieved from http://repositsc.nuczu.edu.ua/handle/123456789/5546

Mohan, D., Sarswat, A., Ok Y.S., & Pittman, Jr. C.U. (2014). Organic and inorganic contaminants remov-al from water with biochar, a renewable, low cost and sustainable adsorbent – a critical re-view. Bioresource Technology, 160, 191–202. https://doi.org/10.1016/j.biortech.2014.01.120

Owens, P.N., & Walling, D.E. (2002), The phosphorus content of fluvial sediment in rural and industri-alized river basins. Water Research, 36(3), 685–701.

Yan Z., Wu L., Lv T., Tong C., Gao Z., Liu Y., ... & Yu D. (2022), Response of spatio-temporal changes in sediment phosphorus fractions to vegetation restoration in the degraded river-lake eco-tone. Environmental Pollution, 308, Article 119650. https://doi.org/10.1016/j.envpol.2022.119650

Humnytskyi, Ya.M., Sabadash, V.V., & Tyzhbir, H.A. (2011). Mechanism of ammonium ion sorption by natural aluminosilicates. Bulletin of the National University “Lviv Polytechnic”. Series: Chemistry, Technology of Substances and Their Application, (726), 308–311. (in Ukrainian)

Nguen, M.L., & Tanner, C.C. (1998). Ammonium removal from wastewaters using natural New Zealand zeolites. New Zealand Journal of Agricultural Research, 41, 427–446.

Klymenko, V.H., & Petrova, N.V. (2011). Assessment of the water quality of the Kharkiv River. Kharkiv: V.N. Karazin Kharkiv National University. (in Ukrainian)

Nabyvanets B.Y., Osadchyi V.I., Osadcha N.M., Nabyvanets Yu.B. (2007). Analytical chemistry of sur-face waters. Ukrainian Hydrometeorological Research Institute. Kyiv: Naukova Dumka. (in Ukrainian)

Bezsonnyi, V., & Nekos, A. (2022). Modeling of the oxygen regime of the Chervonooskilsky reser-voir. Proceedings of the 16th International Conference Monitoring of Geological Processes and Eco-logical Condition of the Environment (Monitoring 2022), Kyiv, Ukraine, 15–18 November 2022. https://doi.org/10.3997/2214-4609.2022580216

Bezsonnyi, V. (2022). Selection of indicative indicators of ecological condition of surface source of water supply. Municipal Economy of Cities (Technical Science), 3(170), 26–34. https://doi.org/10.33042/2522-1809-2022-3-170-26-34

Streeter, H.W., & Phelps, E.B. (1958). A Study of the Pollution and Natural Purification of the Ohio Riv-er. US Public Health Service Bulletin. Retrieved from https://udspace.udel.edu/items/03d5883b-d6e7-4cf6-8a35-e14f9190302f

Ministry of Agrarian Policy and Food of Ukraine. Order on approval of environmental safety standards for water bodies used for fishery purposes regarding maximum permissible concentrations of organic and mineral substances in marine and fresh waters (biochemical oxygen demand (BOD₅), chemical ox-ygen demand (COD), suspended solids, and ammonium nitrogen): 30.07.2012. No. 471 (with amend-ments). Retrieved from https://zakon.rada.gov.ua/laws/show/z1369-12#Text (in Ukrainian)

Ministry of Health of Ukraine. On approval of hygienic standards for water quality of water bodies for drinking, household, and other needs of the population: Order dated 02.05.2022 No. 721 (with amend-ments). Retrieved from https://zakon.rada.gov.ua/laws/show/z0524-22#Text (in Ukrainian)

Published
2025-06-30
How to Cite
HoroshkovаL., Menshov , O. I., Korniichuk, Y. D., Horoshkov, S. V., & Maslov, D. V. (2025). Ecological assessment and forecasting of surface water conditions in the Dnipro river in Zaporizhzhia. Man and Environment. Issues of Neoecology, (43), 47-62. https://doi.org/10.26565/1992-4224-2025-43-04