Structural and lithological model of the Glukhivetsky deposit of eluvial kaolins

Keywords: Vinnytsia region, Glukhiv deposit, eluvial kaolins, structural-lithological model, kaolin thickness, whiteness index, content of titanium and iron oxides

Abstract

Introduction. The relevance of this publication is associated with the problem of foundation and developing a raw material base of kaoline raw material in accordance with the demand of the national industry.

The purpose of the publication is the development of a digital structural-lithological model of the Glukhovetsky deposit, which displays the causal relationship between the geological structure of the crystalline foundation, the zoning and the material composition of the cortex of the crystalline foundation breeds, the thickness and relief of the surface and the sole of the illegal of the kaolins, the indicator of the underlying of the kaolins, the content of the oxids in them by oxides iron and titanium.

Materials and Metodology. The algorithm for building structural and lithological models of kaolin deposits was developed by the authors of the article and tested on a number of deposits of the Ukrainian Shield and made public in scientific publications and at scientific conferences of various levels. Production reports, scientific publications and dissertation studies were the basis for the research of the Hlukhivetsky deposit. Based on the coordinates, description, test results of 691 wells, chemical analysis of kaolins and determination of their whiteness, a target electronic database was created, which became factual material for cartographic constructions. Maps are built in a software environment Golden Software Strater, Golden Software Surfer software. Correlation between certain parameters were investigated in Microsoft Excell.

Main Results. The spatial variability of the relief of the surface and bottom of the deposit of eluvial kaolins and its thickness was studied. It has been found that the kaolin deposit has a complex morphology, which are expressed in significant fluctuations of the absolute marks of its surface and bottom and are caused by the geological and tectonic features of the territory and the erosion of the section. The petrographic and mineral composition of the rocks of the crystalline foundation determined the lateral and vertical variability of the whiteness index, the content of iron and titanium oxides in kaolins, and the lateral and vertical variability of their quality. It was established that the spatial distribution of the whiteness index varies widely (68.1-92.24 %) and is determined by the increased content of Fe2O3 and TiO2, or one of the specified oxides. Sometimes, in the presence of an above-average content of one of the oxides, the whiteness of kaolins is significant. The conducted studies reveal cause-and-effect relationships between the geological and tectonic structure of the deposit, the zoning and material composition of the weathering crust, the relief of the top and bottom of kaolins, their thickness and quality parameters.

Conclusions. The structural-lithological model shows cause-and-effect relationships between the geological and tectonic structure of the deposit, the zoning and material composition of the weathering crust, and the quality parameters of kaolins. The created structural-lithological model is an instrument of information support for further development of the field, as well as the basis for assessing the conditions of education, occurring and quality of raw materials of kaolins of this genetic type.

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Author Biographies

Yulia Kroshko , Institute of Geological Sciences of the NAS of Ukraine

PhD (Geology), Senior Researcher

Myron Kovalchuk , Institute of Geological Sciences of the NAS of Ukraine

DSc (Geology), Professor, Head of the Department of Lithology

References

Geleta O.L. (2014). Mineral resources of Ukraine: clay. Part 2. Characteristics of clay, inspection of their stocks and industries. Pregnant and decorative stones. 4. 16-26.

Bordyugov V.P. (1997). Kaolin (geological and economic review). K.: Geinform.

State Geological Map of Ukraine scale 1: 200 000 sheets M-35-XXIII (Berdychiv) (2001). Kyiv. Ministry of Ecology and Natural Resources of Ukraine. Northern State Regional Geological Enterprise «Pivnich Geology» Pravoberezna GE, 97.

Ivanov Yu.K., Rusko Yu.A., Theodorovich Yu.N. (1971). The mineralogical characteristics of the cortex of the weathering of the Glukhovetsky deposit of primary kaolins. Bark of weathering in the territory of the Ukrainian SSR. Kyiv: Naukova Dumka, 2. 102-123.

Kovalchuk M.S. (2019). Geological and genetic models of weathering of ore-bearing crusts and products of their erosion and redeposition. Achievements and prospects for the development of geological science in Ukraine: Col-lection of theses of the scientific conference dedicated to the 50th anniversary of the M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation (May 14-16, Kyiv). In 2 volumes. Kyiv: NAS of Ukraine, M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation. 2. 53-54.

Kondrachuk V.Yu., Sonkin D.S. (1971). Weathering crust of the Glukhovetsky district of kaolin deposits and struc-tural control of its development. Weathering crusts on the territory of the USSR. Kyiv: Naukova dumka. 2. 123-134.

Kroshko Yu.V., Komalchuk M.S. (2022). Structural and lithological model of the Turbiv deposit of eluvial kaolins. Geological Journal, 1 (378). 50-61: https://doi.org/10.30836/igs.1025-6814.2022.1.244419

Kuzmanenko G.O. (2014). Primary kaolins of the northwestern part of the Ukrainian shield [Text]: Ph (D) thesis. geol. Sciences: 04.00.01, National Academy of Sciences of Ukraine, Institute of Geol. of science. Kyiv. 230.

Lepigov G.D., Vasilenko A.P. (2005). Glukhovetsko-Turbivsky ore node (Geological structure, problems of study). Mineral resources of Ukraine. 2. 13-15.

Metallic and non-metallic minerals of Ukraine. Volume. 2. Non-metallic minerals (2006). D. Gurskyi et al.; edited by M. Shcherbak, S. Goshovskyi. Kyiv-Lviv: Center of Europe. 552.

Remezova E.A., Kuzmanenko H.A. (2013). Models of distribution of kaolins of the Glukhovetsky deposit (Ukraine) on qualitative indicators. Georesources, 5 (55). 16-18.

Rozko A.M., Fedorenko Y.H. (2016). Structure and sorption properties of weathered microcline crystals of the Glu-khovetsky deposit. Mineralogical journal. 38 (4). 39-44.

Rudko G.I., Ozerko V.M., Shepel I.V. (2015). Geology and geological and economic assessment of kaolin deposits of Ukraine / edited by G.I. Rudko. Chernivtsi: Bukrek. 336.

Rusko Yu.A. (1976). Kaolinization and kaolins of the Ukrainian shield. Kyiv: Naukova Dumka. 158.

Salnyk V.G., Chernyak L.P., Petruk R.V. (2007). Comparative analysis of structural-mechanical and rheological indicators of enriched and non-enriched Gluhivtsi kaolins in the technology of production of sanitary ceramics. Bulletin of the Vinnytsia Polytechnic Institute. 6. 16-20.

Slyusarenko H.O. (2009). Lithological characteristics of the weathering crust of the Precambrian rocks of the northwestern part of the Ukrainian shield. Collection of Sciences. works of the Institute of Geol. of Sciences of the National Academy of Sciences of Ukraine. 2. 135-140.

Sushchuk K.G. (2014). Regularities of migration and concentration of thorium in the zone of hypergenesis on the territory of the Ukrainian Shield. Collection of scientific works of the Institute of Geochemistry of the Environ-ment. 23. 148-157.

Tkachuk L.G., Sonkin L.S. (1981). Kaolins of the Glukhovetsko-Turbovsky region of the Ukrainian shield and pro-spects for their use. Kyiv: Naukova Dumka. 291.

Fishkin M.Yu. (1962). Mineralogy and conditions for the formation of kaolins from the Glukhovsky deposit. Miner-al. Collection of the Lvov Geological Society. 16. 227-239.

Khrushchev D.P., Kovalchuk M.S., Remezova E.A. etc. (2017). Structural and lithological modeling of sedimentary formations. Kyiv: Interservice. 352.

Kroshko Y.V., Kovalchuk M.S., Kuzmanenko H.O., Okholina T.V. (2022). Structural and lithological model of the Zhezheliv deposit of eluvial kaolin. Geological Journal. 3 (380): 67-80. https://doi.org/10.30836/igs.1025-6814.2022.3.253551

Published
2024-06-01
Cited
How to Cite
Kroshko , Y., & Kovalchuk , M. (2024). Structural and lithological model of the Glukhivetsky deposit of eluvial kaolins. Visnyk of V. N. Karazin Kharkiv National University, Series "Geology. Geography. Ecology", (60), 40-55. https://doi.org/10.26565/2410-7360-2024-60-03