Fluid regime and ore water of bitumo-hydrothermal mineral associations in the conditions of Western Donetsk graben
Abstract
The fluid regime of bitumen-hydrothermal mineral associations on the ore fields of the Western Donetsk graben, which are part of the Dnieper-Donetsk paleorift, has certain geochemical features. It is conditioned by the peculiarities of geological development, structure and the current level of tectonic activity of the region.
The purpose of the article is to study the fluid regime of bitumen-hydrothermal mineral associations and the participation of hydrocarbons in the hydrothermal process.
The research methodology consisted of a theoretical interpretation of laboratory studies, in particular chemical analyzes of rocks, ore minerals, bitumen, groundwater and gases, as well as isotopic analysis of carbon of solid bitumen.
Research results. Field studies have found that bitumen-hydrothermal mineralization in the rocks is naturally timed to tectonically activate anticlinal structures.
The energy source of its formation are the polychronous processes of heat-and-mass transfer, the power of which is determined by the tectonic activity of the zones of deep faults. In the rocks of the region, with the specified type of ore mineralization (mercury and mercury-polymetallic), the halo waters of a certain geochemical specialization are formed, which include chemical elements of ore and impure minerals and bitumen, as well as endogenous fluids. Among such fluids is the carbon of solid hydrocarbon compounds, the isotopic composition of which indicates its inorganic origin.
The presence of bitumen-hydrothermal mineral associations of chemical elements and gases in halo waters of deep origin indicates that hydrothermal systems of the ore fields of the Western Donetsk graben are on the modern, post-hydrothermal stage of development.
The scientific novelty of the material presented in the article is based on several substantive theoretical conclusions, which are based on the actual material of the research carried out by the authors.
The natural affinity of bitumen-hydrothermal associations to tectonically activate structures located in the zones of deep faults has been proved.
The affinity of inorganic carbon bitumino-hydrothermal mineral associations in solid bitumen and chemical elements present in gas jets and groundwater to metamorphic and mantle processes (He, H2, Hg, CO2, CH4, Li, Rb, Cs, etc.) is substantiated. , which are manifestations of modern tectonic activity of alpine tectogenesis.
It was substantiated that the formation of the chemical composition of the halo waters of bitumen-hydrothermal mineral associations is provided both by exchange chemical processes in the system "mineral-water-gas" and by the income of fluids of deep genesis.
The practical significance of the work is conditioned, on the one hand, by the use of ore hydrothermal mineralization in the rocks as a criterion for the search of hydrocarbon accumulations, and on the other hand, by the prediction of the possibility of hydrocarbon compounds upcoming from large depths in which, in abnormal thermodynamic conditions, an inorganic synthesis of hydrocarbons takes place.
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References
Arsanova, G. I. (1974). Rare alkali in the thermal waters of volcanic areas. Nauka, 111.
Bagrij, I. D. (2016). Water-based hydro-geosynergetic biogenic-mantle hypothesis of hydrocarbon formation and its role in substantiation of search technology. Geologicheskij zhurnal, 2, 107–132.
Bezruk, K. O., Lisichenko, G. V., Suyarko, V. G. (2013). Geochemistry of mercury in underground waters of geological structures of Donetsk folded structure. Kyiv: IGNS of the National Academy of Sciences of Ukraine and KhNU named after VN Karazin,132.
Belokon', V. G. (1984). Bassejn r. Seversky Donets as a geodynamic system that reflects the processes of great depths. Geologicheskij zhurnal, 1, 1–13.
Beskrovnyj, N. S. (1986). Petroleum formation: unity of oil and ore formation. Zhurnal Vsesojuznogo himicheskogo obshhestva imeni D. I. Mendeleeva, 5, 569–574.
Bondarenko, G. N. (1983) Formation of the isotope composition of the carbonate system of natural waters. Nauk.dumka, 152.
Vetshtejn, V.E., Gavrish, V. K., Gucalo, L. K. (1979). Isotope composition of hydrogen and oxygen of waters in deep fault zones. Sov. Geologija, 7, 96-103.
Voznyak, D. K.( 2007) Microinclusion and recon struction of the endogenous mineralization conditions. Naukova dumka,279.
Gavriljuk, O. V. (2015). Paleohydrogeochemical features of bromine accumulation in the south-eastern part of the Dnipro-Donets valley. Serіja: «Geografіchnі ta geologіchnі nauki», 20 (3), 145-153.
Gavrish, V. K., Dobryansky, L. A., Kuril, M. V. (1984) Mercury-hydrocarbon zoning of the Don-Dniprovsky trough DAN USSR, 7, 18-21.
Zaciha, B. V., Petrichenko, O. I., Dolishnij, B. V., Las'kov, V. A. (1973). Origin of mineral formation of the Slavic mercury deposit. Mineralogicheskij sbornik L'vovskogo universiteta, 27, 326–332.
Dobryansky, L. A., Gavrish, V. K. (1988). Paragenesis of mercury and hydrocarbons - an important direction of geological research. Geological Journal, 48, 3-11.
Ishhenko, L. V. (2015). Geochemical criteria for the search of hydrocarbons in the east of the Dnipro-Donets depression. Visny`k XNU imeni V.N.Karazina, 48, 88–93.
Ishhenko L. V. (2016). Patterns of placement of hydrocarbon deposits and zones of hydrothermal mineralization in the territory of the eastern part of the Donetsk folded structure.Visny`k XNU imeni V. N. Karazina, 45, 38–42.
Ishhenko, L. V. (2017). Conditions for the formation of bitumen-hydrothermal associations in the anti-clannic structures of the West-Donetsk graben. Mizhnarodna naukova konferenciya «Geologiya i geoximiya goryuchy`x kopaly`n», pry`svyachenoyi 100-richchyu vid dnya narodzhennya akademika G. N. Dolenka, 69–71.
Kirikilica, S. I., Levenshtejn, M. L., Fridman, A. I. (1972). On the composition and nature of free gas emissions (gas jets) of mercury ore occurrences in the Druzhkov-Kostantinovskaya anticline. Geologicheskij zhurnal, 2, 92–97.
Kononov, V. I. (1983). Geochemistry of thermal waters of modern volcanism (rift zones and island arcs). Nauka, 216.
Ljal'ko, V. I. (1985). Heat and mass transfer in the lithosphere. Naukova dumka,259.
Lukin A. E. (2004). On the formation of fluid-conducting fluid systems in oil and gas basins. Geologicheskij zhurnal, 3, 34–45.
Lukin, A. E., Pikovskii, Yu. I. (2004). On the role of deep and super deep fluids in the processes of oil and gas formation. Geological Journal,2, 21-33.
Maslennikov, V.V. (1987). The similarity of the conditions for the formation of oil gas and mercury deposits,10, 108-114.
Nant, D. E., Anderson, E. T., Grubbs, D. E. (1965). On the probable ore-forming magmatic solution and metamorphosed rocks discovered by a deep well in Southern California. Geohimija sovremennyh postvulkanicheskih processov. Moscow, Russia: Mir,167-171.
Panov, B. S., Korchemagin, V. A., Pilot, I. K. (1974). Isotope composition of oxygen and carbon of Donbas carbonates. DAN USSR, 3, 226–234.
Stebelskaya, G. Ya. A (2017). New View on the Problem of the Classification of Oil. The Bulletin of the VN Karazin KhNU, 46, 50-56.
Stebelskaya, G. Ya. (2017). Regularities of placement of natural bitumen deposits. Geology and Geochemistry of Combustible Minerals, 1, 168-169.
Suyarko, V. G. (2006). Geochemistry of groundwater. Kharkov, KhNU named after VN Karazin,296.
Suyarko, V. G. (1981). Hydrogeochemical features and search criteria for mercury deposits in Donbas. Geological Journal, 2, 147-149.
Suyarko, V.G., Zagnitko, V. M., Lisychenko, G. V. (2010). Structural-geochemical criteria of forecasting of hydrocarbon accumulations (on the example of West-Donetsk graben). Kiev: Salyutis,83.
Suyarko, V.G., Gavryliuk, O. V. (2014). On sources and bromine migration in underground waters (on the example of Dnieper-Donetsk aulacogen). The Bulletin of the Kharkiv National University named after VN Karazin Series: "Geology. Geography. Ecology", 41 (1128), 70-75.
Suyarko, V. G., Ishchenko, L.V., Serdyukova, O.O. (2017). Geochemical features of the hay water of the main types of hydrothermal mineralization of the Donetsk folded structure. Search and ecological geochemistry, 1, 44-51.
Zubkov, V. S., Stepanov, A. N., Karpov, I. K., Bychinsky, V. A. (1998). Thermodynamic model of the СН system under conditions of high temperatures and pressures. Geochemistry, 1, 95-101.
White, E. D. (1970). Deposits of mercury and non-ferrous metals associated with thermal mineral springs. Geochemistry of Ore Deposits. Moscow: The World, 479-524.
Chekalyuk, E. B. (1971). Thermodynamic foundations of mineral origin of oil. Kiev: Naukova Dumka,265.
Khokha, Yu. V. 2014Thermodynamics of deep hydrocarbons in forecasting of regional gas content. Kyyv: Naukova dumka, 56.
Shumlyansky, V. A. (1983). Cimmerian metallogenic epoch on the territory of Ukraine. Kyyv, 234.
James, A. N. (1980). Tow metallogenesic maps for North America. Geol. Rundshall, 69, 594–608.
Giardini, A. A., Melton, C. E. (1982). Evidence that stable carbon isotops are not a reliable criterion for distinguishing biogenetic from non-biogenic petroleum. Petrol. Geol., 4, 437–439.
Ellis, A. I., Mahon, W. A. (1964). Natural hydrothermal sestems and experimental hot water. Geohim. et Cosmochim. Acta, 8, 1323-1357.
Mollex, G., Furi, E., Burnard, P. (2018). Tracing helium isotope compositions from mantle source to fumaroles at Oldoinyo Lengai volcano, Tanzania. Chemical Geology, 480, 66–74.
White, D. E. (1957). Magmatic, connate and metarmorphic water. Bull. Geol.Soc.Amer, 12, 1659-1682.