Синтез та характеристика наноструктур (PVA-CoO-ZrO2) для нанооптоелектронних застосувань
Анотація
Нанокомпозити мають багато застосувань, включаючи оптичні інтегральні схеми, датчики, покриття та медичні пристрої. У зв’язку з цим метою цієї роботи є отримання нового типу нанокомпозитів з полівінілового спирту (ПВС) з різними концентраціями (0, 1, 2 і 3) мас.% оксиду кобальту та діоксиду цирконію (CoO-ZrO2) наночастинок методом лиття. Мікроскопічні фотографії демонструють, що додаткова кількість наночастинок у полімері була рівномірною, і наночастинок (CoO ZrO2) утворювали безперервну мережу в полімері, коли концентрація досягала 3 мас.%. Крім того, результати оптичних властивостей вказують на те, що поглинання нанокомпозитів покращується, оскільки концентрація наночастинок оксиду кобальту та діоксиду цирконію збільшується під час пропускання та зменшується розрив візуальної енергії. З іншого боку, оптичні константи нанокомпозитів (показник заломлення, коефіцієнт поглинання, коефіцієнт екстинкції, дійсна та уявна діелектричні константи) і оптична провідність зростають зі збільшенням масових часток (CoO-ZrO2) наночастинок. Ці результати демонструють використання наночастинок PVA-CoO-ZrO2 для різних оптичних пристроїв.
Завантаження
Посилання
M. Khairy, and M.E. Gouda, “Electrical and optical properties of nickel ferrite/polyaniline nanocomposite,” J. Adv. Res. 6(4), 555-562 (2015). https://doi.org/10.1016/j.jare.2014.01.009
A.H. Hadi, and M.A. Habeeb, “The dielectric properties of (PVA-PVP-CdS) nanocomposites for gamma shielding applications,” Journal of Physics: Conference Series, 1973(1), 012063 (2021). https://doi.org/10.1088/1742-6596/1973/1/012063
S.K. Sharma, J. Prakash, K. Sudarshan, D. Sen, S. Mazumder, and P. K. Pujari, “Structure at interphase of poly (vinyl alcohol)–SiC nanofiber composite and its impact on mechanical properties: positron annihilation and small-angle X-ray scattering studies,” Macromolecules, 48 (16), 5706–5713 (2015). https://doi.org/10.1021/acs.macromol.5b01095
S.M. Mahdi , and M.A. Habeeb, “Fabrication and Tailored Structural and Dielectric characteristics of (SrTiO3/NiO) Nanostructure Doped (PEO/PVA) polymeric Blend for Electronics Fields,” Physics and Chemistry of Solid State, 23 (4), 785-792 (2022) . https://doi.org/10.15330/pcss.23.4.785-792
H.J. Zhou, M.Z. Rong, M.Q. Zhang, and K. Friedrich, “Effects of reactive compatibilization on the performance of nano-silica filled polypropylene composites,” J. Mater. Sci. 41(17), 5767–5770 (2006). https://doi.org/10.1007/s10853-006-0112-x
S.M. Mahdi, and M.A. Habeeb, “Low-cost piezoelectric sensors and gamma ray attenuation fabricated from novel polymeric nanocomposites,” AIMS Materials Science, 10(2), 288–300 (2023). https://doi.org/10.3934/matersci.2023015
W.J. Qi, R. Nieh, B.H. Lee, L. Kang, Y. Jeon, and J.C. Lee, “Electrical and reliability characteristics of ZrO 2 deposited directly on Si for gate dielectric application,” Appl. Phys. Lett. 77(20), 3269–3271 (2000). https://doi.org/10.1063/1.1326482
S.M. Mahdi, and M.A. Habeeb, “Evaluation of the influence of SrTiO3 and CoO nanofillers on the structural and electrical polymer blend characteristics for electronic devices,” Digest Journal of Nanomaterials and Biostructures, 17(3), 941-948 (2022). https://doi.org/10.15251/DJNB.2022.173.941
J.C. Toniolo, A.S. Takimi, and C.P. Bergmann, “Nanostructured cobalt oxides (Co3O4 and CoO) and metallic Co powders synthesized by the solution combustion method,” Mater. Res. Bull. 45(6), 672–676 (2010). https://doi.org/10.1016/j.materresbull.2010.03.001
M.A. Habeeb, "Effect of rate of deposition on the optical parameters of GaAs films,” European Journal of Scientific Research, 57(3), 478-484 (2011).
J. Hoffmann, I. Řeznı́čková, J. Kozáková, J. Růžička, P. Alexy, D. Bakoš, and L. Precnerová, “Assessing biodegradability of plastics based on poly (vinyl alcohol) and protein wastes,” Polym. Degrad. Stab. 79(3), 511–519 (2003). https://doi.org/10.1016/S0141-3910(02)00367-1
N. Hayder, M.A. Habeeb, and A. Hashim, “Structural, optical and dielectric properties of (PS-In2O3/ZnCoFe2O4) nanocomposites,” Egyptian Journal of Chemistry, 63, 577-592 (2020). https://dx.doi.org/10.21608/ejchem.2019.14646.1887
Q.M. Jebur, A. Hashim, and M.A. Habeeb, “Structural, A.C electrical and optical properties of (polyvinyl alcohol-polyethylene oxide-aluminum oxide) nanocomposites for piezoelectric devices,” Egyptian Journal of Chemistry, 63, 719-734 (2020). https://dx.doi.org/10.21608/ejchem.2019.14847.1900
J. Lee, D. Bhattacharyya, A.J. Easteal, and J.B. Metson, “Properties of nano-ZnO/poly (vinyl alcohol)/poly (ethylene oxide) composite thin films,” Curr. Appl. Phys., 8(1), 42–47 (2008).
M.A. Habeeb, A. Hashim, and N. Hayder, “Fabrication of (PS-Cr2O3/ZnCoFe2O4) nanocomposites and studying their dielectric and fluorescence properties for IR sensors,” Egyptian Journal of Chemistry, 63, 709-717 (2020). https://dx.doi.org/10.21608/ejchem.2019.13333.1832
A. Hashim, M.A. Habeeb, and Q.M. Jebur, “Structural, dielectric and optical properties for (Polyvinyl alcohol-polyethylene oxide manganese oxide) nanocomposites,” Egyptian Journal of Chemistry, 63, 735-749 (2020). https://dx.doi.org/10.21608/ejchem.2019.14849.1901
E. Randjbaran, R. Zahari, and R. Vaghei, “Scanning Electron Microscopy Interpretation In Carbon Nanotubes Composite Materials After Postbuckling-Review Paper,” MATRIX Acad. Int. Online J. Eng. Technol. 2(2), 1–6 (2014).
Q.M. Jebur, A. Hashim, and M.A. Habeeb, “Fabrication, structural and optical properties for (Polyvinyl alcohol-polyethylene oxide iron oxide) nanocomposites,” Egyptian Jour of Chemistry, 63 (2), 611-623 (2020). https://dx.doi.org/10.21608/ejchem.2019.10197.1669
M.A. Habeeb, and W.S. Mahdi, “Characterization of (CMC-PVP-Fe2O3) nanocomposites for gamma shielding application,” International Journal of Emerging Trends in Engineering Research, 7 (9), 247-255 (2019). https://dx.doi.org/10.30534/ijeter/2019/06792019
R. Tintu, K. Saurav, K. Sulakshna, V.P.N. Nampoori, P. Radhakrishnan, and S. Thomas, “Ge28Se60Sb12/PVA composite films for photonic applications,” J. Non-Oxide Glas. 2(4), 167–174 (2010).
M.A. Habeeb, and R.S.A. Hamza, “Synthesis of (polymer blend –MgO) nanocomposites and studying electrical properties for piezoelectric application,” Indonesian Journal of Electrical Engineering and Informatics, 6(4), 428-435 (2018). https://dx.doi.org/10.11591/ijeei.v6i1.511
M.A. Habeeb, and R.S. Abdul Hamza, “Novel of (biopolymer blend-MgO) nanocomposites: Fabrication and characterization for humidity sensors,” Journal of Bionanoscience, 12 (3), 328-335 (2018). https://doi.org/10.1166/jbns.2018.1535
J. Selvi, S. Mahalakshmi, and V. Parthasarathy, “Synthesis, structural, optical, electrical and thermal studies of polyvinyl alcohol/CdO nanocomposite films,” Journal of Inorganic and Organometallic Polymers and Materials, 27, 1918-1926 (2017).
M.A. Habeeb, A. Hashim, and N. Hayder, “Structural and optical properties of novel (PS-Cr2O3/ZnCoFe2O4) nanocomposites for UV and microwave shielding,” Egyptian Journal of Chemistry, 63, 697-708 (2020). https://dx.doi.org/10.21608/ejchem.2019.12439.1774
M.A. Habeeb, W.K. Kadhim, “Study the optical properties of (PVA-PVAC-Ti) nanocomposites,” Journal of Engineering and Applied Sciences, 9 (4), 109-113(2014). https://doi.org/10.36478/jeasci.2014.109.113
R. Tintu, K. Saurav, K. Sulakshna, V.P.N. Nampoori, P. Radhakrishnan, and S. Thomas, “Ge28Se60Sb12/PVA composite films for photonic applications,” J. Non-Oxide Glas. 2, (4), 167–174 (2010)
A.H. Hadi, and M.A. Habeeb, “Effect of CdS nanoparticles on the optical properties of (PVA-PVP) blends,” Journal of Mechanical Engineering Research and Developments, 44(3), 265 – 274 (2021). https//jmerd.net/03-2021-265-274/
D.S. McLachlan, C. Chiteme, C. Park, K.E. Wise, Sh.E. Lowther, P.T. Lillehei, E.J. Siochi, and J.S. Harrison, “AC and DC percolative conductivity of single wall carbon nanotube polymer composites,” Journal of Polymer Sciences Part B, 43(22) 3273 3287 (2005).
S.M. Mahdi, and M.A. Habeeb, “Synthesis and augmented optical characteristics of PEO–PVA–SrTiO3–NiO hybrid nanocomposites for optoelectronics and antibacterial applications,” Optical and Quantum Electronics, 54(12), 854 (2022). https://doi.org/10.1007/s11082-022-04267-6
M.A. Habeeb, “Dielectric and optical properties of (PVAc-PEG-Ber) biocomposites,” Journal of Engineering and Applied Sciences, 9 (4), 102-108 (2014). https://doi.org/10.36478/jeasci.2014.102.108
G. Shui, J. Hu, M. Qiu, M. Wei, D. Xiao, “Study of Dielectric Properties For (Calcium Oxide-poly-vinyl alcohol) Composites,” Chinese Chem. letters, 15(12), 1501-1504 (2004).
M.A. Habeeb, and W.H. Rahdi, “Titanium carbide nanoparticles filled PVA‑PAAm nanocomposites, structural and electrical characteristicsfor application in energy storage,” Optical and Quantum Electronics, 55 (4), 334 (2023). https://doi.org/10.1007/s11082-023-04639-6
V.M. Bhargav, P.B. Mohan, V. Raja, A.K. Sharma, and V.V.R.N. Rao, “Optical and Electrical Properties of Pure and Doped PEO Polymer Electrolyte Films,” Soft Mater, 5, 33–46 (2007). https://dx.doi.org/10.1080/15394450701405291
M.A. Habeeb, and Z.S. Jaber, “Enhancement of Structural and Optical Properties of CMC/PAA Blend by Addition of Zirconium Carbide Nanoparticles for Optics and Photonics Applications,” East European Journal of Physics, 4, 176-182 (2022). https://doi.org/10.26565/2312-4334-2022-4-18
S.M. Mahdi, M.A. Habeeb, “Tailoring the structural and optical features of (PEO–PVA)/(SrTiO3–CoO) polymeric nanocomposites for optical and biological applications,” Polymer Bulletin, (2023). https://doi.org/10.1007/s00289-023-04676-x
K.R. Nemade, S.A. Waghuley, “Synthesis of MgO nanoparticles by solvent mixed spraypyrolysis technique for optical investigation,” Int. J. Metals, 2014 (4), (2014), Article ID 389416, http://dx.doi.org/10.1155/2014/389416
M.H. Dwech, M.A. Habeeb, and A.H. Mohammed, “Fabrication and Evaluation of Optical Characterstic of (PVA-MnO2–ZrO2) Nanocomposites for Nanodevices in Optics and Photonics,” Ukr. J. Phys. 67(10), 757-762 (2022). https://doi.org/10.15407/ujpe67.10.757
A.A. Mohammed, and M.A. Habeeb, “Modification and Development of the Structural, Optical and Antibacterial Characteristics of PMMA/Si3N4/TaC Nanostructures,” Silicon, (2023), https://doi.org/10.1007/s12633-023-02426-2
A. Gautam, and S. Ram, “Preparation and Thermomechanical Properties of Ag-PVA Nanocomposite Films,” Mater. Chem. Phys. 119 (2), 266-271 (2010)
N.K. Al‑Sharifi, and M.A. Habeeb, “Synthesis and Exploring Structural and Optical Properties of Ternary PS/SiC/Sb2O3 Nanocomposites for Optoelectronic and Antimicrobial Applications,” Silicon, (2023), https://doi.org/10.1007/s12633-023-02418-2
N.B.V. Crasta, R. Kumar, and B.M. Praveen, “Advancement in Microstructural, Optical, and Mechanical Properties of PVA (Mowiol 10-98) Doped by ZnO Nanoparticles,” Physics Research International, 9(3), (2014), https://doi.org/10.1155/2014/742378
Цитування
Synthesis and tailoring the morphological, structural and optical characteristics of SiO2–CO2O3 nanomaterials doped PVA–PEG for optoelectronic and food packing applications
Kadhim Waleed Khalid & Habeeb Majeed Ali (2024) Optical and Quantum Electronics
Crossref
Influence of irradiation on modifying the surface wettability and optical characteristics of flexible polymer composite films for optoelectronic devices
Atta A., Altuijri Reem, Al-Harbi Nuha & Abdel Reheem A. M. (2026) International Journal of Polymer Analysis and Characterization
Crossref
Fabrication and Evaluation the Optical and Dielectric Characteristics of Promising PVA-ZrC-SiO2 Nanocompsites Films
Habeeb Majeed Ali, Hamza Rehab Shather Abdul, Oreibi Idrees & Sabur Dhay Ali (2024) Silicon
Crossref
Preparation and Modulation of the Morphological, Structural, Electrical, Dielectric and Linear/Nonlinear Optical Characteristics of PVA-PVP/SiC-Bi2O3 Nancomposites for Energy Storage Devices and Radiation Attenuation
AL-Issawe Jassim M., Habeeb Majeed Ali & Abdulridha Ali R. (2025) Silicon
Crossref
Structural and Dielectric Parameters of PVA/CMC Blend Reinforced with SiO2/SnO2 Nanoparticles for Nanoelectronics Applications
Abdul Hamza Rehab Shather & Habeeb Majeed Ali (2024) Transactions on Electrical and Electronic Materials
Crossref
Preparation and Dielectric Properties of Polymer Nanocomposites for Dielectric Applications
(2024) Nanosistemi, Nanomateriali, Nanotehnologii
Crossref
Fabrication and Adapting the Morphological, Structural, Optical and Dielectric Performance of PS-ZrC-SiO2 Nanocomposite Films for Optoelectronic and Energy Storage Applications
Habeeb Majeed Ali, Kadhim Waleed Khalid, Mamoun Fellah & Abdulkhudher Bashaer A. (2025) Silicon
Crossref
Structural and A.C. Electrical Properties of Polyvinyl Alcohol/Iron Oxide Nanocomposites for Electronic and Electrical Applications
(2024) Nanosistemi, Nanomateriali, Nanotehnologii
Crossref
Enhancing the multifunctional properties of polycaprolactone/chitosan films with zirconium dioxide nanoparticles for biomedical and flexible optoelectronic applications
Kahdim Qasim Shakir, Benzarti Zohra, Mousa Mohanad H., Rasheed Maher Hassan, Abdelmoula Najmeddine & Khalfallah Ali (2025) RSC Advances
Crossref
Thiolation and PEGylation of silicon carbide nanoparticles
Rózsa Péter, Krafcsik Olga, Czigány Zsolt, Lenk Sándor, Beke David & Gali Adam (2025) Results in Chemistry
Crossref
Synthesis and Tuning the Structural, Optical and Electrical Behavior of PVA-SiC-BaTiO3 Polymer Nanostructures for Photonics and Electronics Nanodevices
Habeeb Majeed Ali & Kadhim Waleed Khalid (2024) Journal of Inorganic and Organometallic Polymers and Materials
Crossref
Modification and Development of the Structural, Morphological and Dielectric Characteristics of Polyvinyl Alcohol Incorporated with Cerium Dioxide / Silicon Carbide Nanoparticles for Nanodielectric and Nanoelectronic Applications
Abdel-Amir Ali Hussein & Habeeb Majeed Ali (2024) Silicon
Crossref
Modifying of structural, dielectric, electrical conductivity and linear/nonlinear optical properties of PVA doped with MnO2-SiO2 nanoparticles for optoelectronic and radiation attenuation applications
Habeeb Majeed Ali, Kadhim Waleed Khalid, Fellah Mamoun & Elboughdiri Noureddine (2025) Solid State Sciences
Crossref
Boosting the morphological, structural, optical, and dielectric characteristics of MgO-SiC nanomaterials merged with organic polymer for high-performance energy storage devices
Habeeb Majeed Ali, Oreibi Idrees & Hamza Rehab Shather Abdul (2025) Journal of Materials Science: Materials in Electronics
Crossref
Tailoring the Structural and Optical Features of PVA/SiO2-CuO Polymeric Nanocomposite for Optical and Gamma Ray Shielding Applications
Oreibi Idrees, Habeeb Majeed Ali & Hamza Rehab Shather Abdul (2024) Silicon
Crossref
Antimony (III) oxide and calcium phosphate doped with carbon nanotubes in PVA/HA matrix for wound dressing applications
Elabbasy Mohamed Tharwat, Almarshadi Fahad Awwadh, Alshammari Muteb H., Othman Mohamed S., Ghoniem Mohamed E., Samak Mai A., Domyati Doaa, El-Morsy M.A. & Farea M.O. (2025) Materials Chemistry and Physics
Crossref
Effect of ZrO2–CuO Nanofiller on the Optical Constants and Optical Conductivity of Biopolymer
(2024) Nanosistemi, Nanomateriali, Nanotehnologii
Crossref
Ameliorating and Tailoring The Morphological, Structural, and Dielectric Characteristics of SiO2 /NiO Futuristic Nanocomposites Doped PVA-PEG for Nanoelectronic and Energy Storage Applications
Kadhim Waleed Khalid & Habeeb Majeed Ali (2024) Silicon
Crossref
Exploring the Optical Properties of BaTiO3/CuO-Nanoparticles-Doped PVA Polymer for Optoelectronic Applications
(2024) Nanosistemi, Nanomateriali, Nanotehnologii
Crossref
Two-dimension MoS2/Ti3C2 MXene nanocomposite for an efficient hydrogen evolution reaction in alkaline media
Hasanah Rachmadani, Romdoni Yoga, Fauzia Vivi, Arifutzzaman A., Hussin Farihahusnah, Aroua Mohamed Kheireddine & Khalil Munawar (2025) Materials Research Bulletin
Crossref
Fabrication and Exploring the Morphological, Structural and Optical Characteristics of Polyvinyl Alchol—Carboxymethyl Cellulose—Silicon Dioxide—Tin Dioxide Nanostructures for Optoelectronics and Antibacterial Applications
Hamza Rehab Shather Abdul & Habeeb Majeed Ali (2024) Silicon
Crossref
Effect of WC-Nanoparticles' Addition on the Structural and Dielectric Characteristics of a Biopolymer
(2025) Nanosistemi, Nanomateriali, Nanotehnologii
Crossref
Enhancement Structural Properties and Optical Energy Gap of PVA–ZrO2–CuO Nanostructures for Optical Nanodevices
(2024) Nanosistemi, Nanomateriali, Nanotehnologii
Crossref
Enhancement of Structural and Dielectric Properties of PVA–BaTiO3–CuO Nanostructures for Electronic and Electrical Applications
(2024) Nanosistemi, Nanomateriali, Nanotehnologii
Crossref
Fabrication and development morphological, structural, dielectric, linear and nonlinear optical properties of PS/BaTiO3-SiC nanocomposites for optoelectronic and energy storage applications
Habeeb Majeed Ali, Oreibi Idrees & Hamza Rehab Shather Abdul (2025) Emergent Materials
Crossref
Multifunctional polyvinyl alcohol /
maranta arundinacea
starch /LiAgO nanocomposites: A sustainable approach for antibacterial and optoelectronic applications
Shabah N Najmu, Rahman TT Khaleelul, Gopika R & Ramesan MT (2026) Journal of Thermoplastic Composite Materials
Crossref
Effect of CdSe nanoparticles doping on structural, and linear/nonlinear optical properties of PVC polymer for optoelectronic devices
Almutlaq Nasser, Ibrahim A, Henaish AMA & Abdelhamied MM (2026) Journal of Thermoplastic Composite Materials
Crossref
Optoelectronic exploration of two pyrazole-based oligomers: synthesis, characterization, theoretical calculations, and optical properties of thin films
Cetin Adnan & Bildirici Ishak (2025) Spectroscopy Letters
Crossref
Tailoring the properties of PVA/MWCNT nanocomposites: a focus on structural, electrical, and thermal behavior
Noori Farah T. M., Hussein Seenaa I., Ali Nadia A., Polu Anji Reddy, Muslim Zainab R., Jawad Mohammed K., Kareem Aseel A. & Ismail Hani K. (2026) Fullerenes, Nanotubes and Carbon Nanostructures
Crossref
Авторське право (c) 2023 Зейнаб Сабрі Джабер, Маджід Алі Хабіб, Валід Хаді Раді

Цю роботу ліцензовано за Міжнародня ліцензія Creative Commons Attribution 4.0.
Автори, які публікуються у цьому журналі, погоджуються з наступними умовами:
- Автори залишають за собою право на авторство своєї роботи та передають журналу право першої публікації цієї роботи на умовах ліцензії Creative Commons Attribution License, котра дозволяє іншим особам вільно розповсюджувати опубліковану роботу з обов'язковим посиланням на авторів оригінальної роботи та першу публікацію роботи у цьому журналі.
- Автори мають право укладати самостійні додаткові угоди щодо неексклюзивного розповсюдження роботи у тому вигляді, в якому вона була опублікована цим журналом (наприклад, розміщувати роботу в електронному сховищі установи або публікувати у складі монографії), за умови збереження посилання на першу публікацію роботи у цьому журналі.
- Політика журналу дозволяє і заохочує розміщення авторами в мережі Інтернет (наприклад, у сховищах установ або на особистих веб-сайтах) рукопису роботи, як до подання цього рукопису до редакції, так і під час його редакційного опрацювання, оскільки це сприяє виникненню продуктивної наукової дискусії та позитивно позначається на оперативності та динаміці цитування опублікованої роботи (див. The Effect of Open Access).



