Electric Field Enhancement by Gold Nano-Sphere and Its Clusters
Abstract
The confinement of electrons in gold nanoparticles results in Surface Plasmon Resonance (SPR), which is characterized by electric field enhancement in the vicinity of these nanoparticles. This property has been extensively studied and applied in various fields. In our research, we conduct a detailed investigation of plasmonic coupling in spherical gold nanoparticles. Specifically, we use the Discrete Dipole Approximation (DDA) method implemented in DDSCAT to simulate the coupling of electric fields in a doublet of nanoparticles as a function of the distance between them. Our simulations show that the coupling of SPR between two nanoparticles occurs up to a separation of 12 nm. Moreover, we extend our simulations to study the coupling of nanoparticles in linear chains consisting of up to five nanoparticles and in clustered forms. Our results indicate that the SPR coupling in a linear chain occurs, and as the number of nanoparticles increases, the field enhancement also increases. However, we observe that this effect saturates after four nanoparticles in a line. Our study provides insights into the plasmonic coupling in gold nanoparticles, which can aid in the design and optimization of plasmonic devices for various applications.
Downloads
References
C.N. Banwell and E.M. Mc-Cash, Fundamentals of molecular spectroscopy, 4th Edition, (Tata Mc Graw Hill, India, 1995).
F. Lu, W. Zhang, L. Sun, T. Mei, and X. Yuan, Optics Express, 30, 12 21377 (2022). https://doi.org/10.1364/OE.460394
L. Meng, Y. Wang, M. Gao, and M. Sun, J. Phys. Chem. C, 125, 10 5684 (2021). https://doi.org/10.1021/acs.jpcc.0c10922.
A. Szaniawska, and A. Kudelski, Frontiers in Chemistry, 9, 664134 (2021). https://doi.org/10.3389/fchem.2021.664134.
H. Zhou, X. Li, L. Wang, Y. Liang, A. Jialading, Z. Wang, and J. Zhang, Reviews in Analytical Chemistry, 40 (1), 173 (2021). https://doi.org/10.1515/revac-2021-0132
M.M. Joseph, N. Narayanan, J.B. Nair, V. Karunakaran, A.N. Ramya, P.T. Sujai, et al., Biomaterials, 181,140 (2018). https://doi.org/10.1016/j.biomaterials.2018.07.045
S. Khan, R. Ullah, A. Khan, R. Ashraf, H. Ali, M. Bilal, and M. Saleem, Photo diagnosis and Photodynamic Therapy, 23,89 (2018). https://doi.org/10.1016/j.pdpdt.2018.05.010
D.W. Shipp, F. Sinjab, and I. Notingher, Advances in Optics and Photonics, 9(2), 315 (2017). https://doi.org/10.1364/AOP.9.000315
J. Parsons, C.P. Burrows, J.R. Sambles and W.L. Barnes, Journal of Modern Optics, 57, 1362 (2010). https://doi.org/10.1080/09500341003628702
B.T. Draine, and P.J. Flatau, J. Opt. Soc. Am. A,11,1491 (1994). https://doi.org/10.1364 /JOSAA.11. 001491
B.T. Draine, and J. Goodman, The Astrophysics journal, 405, 685 (1993). https://doi.org/10.1086/172396
B.T. Draine, and P. J. Flatau, J. Opt. Soc. Am. A,25 (11),2693 (2008). https://doi.org/10.1364/JOSAA.25.002693
M.A. Yurkin, and M. Huntemann, J. Phys. Chem. C, 119, 52, 29088 (2015). https://doi.org/10.1021/acs.jpcc.5b09271
C. Mätzler, MATLAB Functions for Mie Scattering and Absorption, (Institute of Applied Physics, University of Bern, 2002). https://omlc.org/software/mie/maetzlermie/Maetzler2002.pdf
P.B. Johnson, and R.W. Christy, Phys. Rev. B, 6, 4370 (1972). https://doi.org/10.1103/PhysRevB.6.4370
Copyright (c) 2024 P.K. Kushwaha, K.Y. Singh, Himmat Singh Mahor, Pramod Kumar Singh, Ravish Sharma, Kash Dev Sharma
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).