Investigation of Structural, Magnetic and Optical Properties for Dysprosium Doped Zinc Nanoferrites by Sol-Gel Autocombution Techniques
Abstract
Using the auto combustion sol-gel method, nanoferrite crystalline aligns of Dy3+ replaced Zn-Fe spinel ferrite with the chemical formula DyxZn1-xFe2-xO4 (x= 0.00, 0.05) were successfully synthesized. In this process, citric acid was utilized as energy (fuel) in a 3:1 ratio to metal nitrate. Using XRD and FT-IR, the crystal structure and phase of dysprosium zinc was examined. Using the XRD method, the crystal size, lattice constant, cation distribution, and porosity were ascertained. FT-IR spectroscopy is used to infer structural study and the redistribution of cations between octahederal (A) and tetrahederal (B) site of Zn material. According to morphological research, the temperature during sintering is what causes grain to form and grow. Utilizing the Hysteresis Loop Technique, saturation magnetism and magneton number are determined. In Zn-Fe ferrite, the saturation magnetization rises with increasing density x, utilizing the Sol-gel auto-combustion method at a comparatively low temperature. Using nitrate citrate, the nanocrystallite DyxZn1-xFe2-xO4 was created. The combustion process and chemical gelation are unique. Using citric acid as a catalyst, their metal nitrates nanoferrites underwent a successful chemical reaction and were obtained as a dried gel. FT-IR, UV-Visible, VSM and XRD were used to characterize the produced nanoferrite powders. Magnetization and hysteresis were measured using the VSM technique. The FT-IR verifies that the synthesized substance is ferrite. The size of the nanocrystalline ferrite material, DyxZn1-xFe2-xO4, was determined by X-ray using the Scherrer method to be between 16.86 to 12.72 nm average crystallite size. Magnetization and hysteresis were measured using the VSM technique.
Downloads
References
N. Rezlescu, E.C. Rezlescu, and M.L. Craus, “Effects of the rare-earth ions on some properties of a nickel-zinc ferrite,” J. Phys. Condens. Matter. 6, 5707 (1994). https://doi.org/10.1088/0953-8984/6/29/013
S. Solyman, “Transport properties of La-doped Mn–Zn ferrite,” Ceram. Int. 32, 755-760 (2006). https://doi.org/10.1016/j.ceramint.2005.05.018
A.A. Sattar, and K.M. EI-Shokrofy, “Rare Earth Doping Effect on the Electrical Properties of Cu-Zn Ferrites,” J. Phys. 7(1), C1-245-C1-246 (1997). https://doi.org/10.1051/jp4:1997194
N. Rezlescu, E. Rezlescu, P.D. Mangeron, L. Rezlescu, and C. Pasnicu, “The Influence of R2O3 (R = Yb, Er, Dy, Tb, Gd, Sm and Ce) on the Electric and Mechanical Properties of a Nickel–Zinc Ferrite,” J. Phys. C: State Solid, 162, 673-678 (1997). https://doi.org/10.1002/1521-396X(199708)162:2%3C673::AID-PSSA673%3E3.0.CO;2-A
P.K. Roy, B.B. Nayak, and J. Bera, “Study on electro-magnetic properties of La substituted Ni–Cu–Zn ferrite synthesized by auto-combustion method,” J. Magn. Magn. Mater. 320, 1128-1132 (2008). https://doi.org/10.1016/j.jmmm.2007.10.025
A.A. Sattar, A.H. Wafik, K.M. EI-Shokrofy, and M.M. EI-Tabby, “Magnetic Properties of Cu–Zn Ferrites Doped with Rare Earth Oxides,” Status Solidi a, 171, 563-569 (1999). https://doi.org/10.1002/(SICI)1521-396X(199902)171:2%3C563::AID-PSSA563%3E3.0.CO;2-K
B. Azhdar, B. Stenberg, and L. Kari, “Polymer–nanofiller prepared by high-energy ball milling and high velocity cold compaction,” Polymer Composites, 29, 252-261 (2008). https://doi.org/10.1002/pc.20353
N. Javerberg, H. Edin, P. Nordell, S. Nawaz, B. Azhdar, and U.W. Gedde, “Dielectric properties of alumina-filled poly (ethylene-co-butyl acrylate) nanocomposites. Part I-dry studies,” IEEE Trans. Dielectr. Electr. Insul. 19(2), 383 390 (2012). https://doi.org/10.1109/TDEI.2012.6180229
J. Peng, M. Hojamberdiev, Y. Xu, B. Cao, J. Wang, and H. Wu, “Hydrothermal synthesis and magnetic properties of gadolinium-doped CoFe2O4 nanoparticles,” J. Magn. Magn. Mater. 323(1), 133-137 (2011). https://doi.org/10.1016/j.jmmm.2010.08.048
M.A. Almessiere, Y. Slimani, S. Guner, M. Sertkol, A. Demir Korkmaz, S.E. Shirsath, and A. Baykal, “Sonochemical synthesis and physical properties of Co0.3Ni0.5Mn0.2EuxFe2−xO4 nano-spinel ferrites,” Ultrasonics Sonochemistry, 58, 104654 (2019). https://doi.org/10.1016/j.ultsonch.2019.104654
V.S. Rizi, F. Sharifianjazi, H. Jafarikhorami, N. Parvin, L.S. Fard, M. Irani, and A. Esmaeilkhanian, “Sol–gel derived SnO2/Ag2O ceramic nanocomposite for H2 gas sensing applications,” Materials Research Express, 6, 1150g-1152g (2019); https://doi.org/10.1088/2053-1591/ab511e
R.S. Yadav, I. Kuřitka, J. Vilcakova, J. Havlica, L. Kalina, P. Urbánek, M. Machovsky, et al., “Sonochemical synthesis of Gd3+ doped CoFe2O4 spinel ferrite nanoparticles and its physical properties,” Ultrason. Sonochem. 40, 773 783 (2018). https://doi.org/10.1016/j.ultsonch.2017.08.024
P. Ravindranathan, and K.C. Patil, “A low temperature path to the preparation of ultrafine ferrites,” Ceram. Bull. 66, 688-692 (1987). http://eprints.iisc.ac.in/id/eprint/13867
I.K. Punithavathy, A. Rajeshwari, S.J. Jeyakumar, N. Lenin, B. Vigneshwaran, M. Jothibas, and B. Arunkumar, “Impact of lanthanum ions on magnetic and dielectric properties of Zinc nanoferrites,” J. Mater. Sci. Mater. Electron. 31, 9783–9795 (2020). https://doi.org/10.1007/s10854-020-03523-3
K.L. Routray, S. Saha, and D. Behera, “Rare-earth (La3+) substitution induced changes in the structural, dielectric and magnetic properties of nano- CoFe2O4 for highfrequencyand magneto-recording devices,” Appl. Phys. A, 125, 328 (2019). https://doi.org/10.1007/s00339-019-2615-8
S.B. Das, R.K. Singh, V. Kumar, N. Kumar, P. Singh, and N.K. Naik, “Structural, magnetic, optical and ferroelectric properties of Y3+ substituted zinc ferrite nanomaterials prepared by a cost-effective sol-gel route,” Mater. Sci. Semicond. Process. 145, 106632 (2022). https://doi.org/10.1016/j.mssp.2022.106632
S.S. Satpute, S.R. Wadgane, K. Desai, D.R. Msne, and R.H. Kadam, “Substitution effect of Y+3 ions on the structural, magnetic and electrical properties of zinc ferrite nanoparticles,” Ceramica, 66, 43–49 (2020). https://doi.org/10.1590/0366-69132020663772734
K.V. Kumar, “Tunable optical bandgap of gadolinium substituted nickel-zinc ferrite nanoparticles-effect of calcination temperature on its optical parameters,” Advances in Materials Physics and Chemistry, 12, 33–45 (2022). https://doi.org/10.4236/ampc.2022.123003
M. Rashad, R. Mohamed, and H. El-Shall, “Magnetic properties of nanocrystalline Sm-substituted CoFe2O4 synthesized by citrate precursor method,” J. Mater. Process. Technol. 198, 139-146 (2008). https://doi.org/10.1016/j.jmatprotec.2007.07.012
F.-X. Cheng, J.-T. Jia, Z.-G. Xu, B. Zhou, C.-S. Liao, C.-H. Yan, L.-Y. Chen, and H.- B. Zhao, “Microstructure, magnetic, and magneto-optical properties of chemical synthesized Co-RE (RE¼ Ho, Er, Tm, Yb, Lu) ferrite nanocrystalline films,” J. Appl. Phys. 86, 2727-2732 (1999). https://doi.org/10.1063/1.371117
A. Gadkari, T. Shinde, and P. Vasambekar, “Structural analysis of Y3+-doped Mg-Cd ferrites prepared by oxalate co-precipitation method,” Mater. Chem. Phys. 114, 505-510 (2009). https://doi.org/10.1016/j.matchemphys.2008.11.011
J. Peng, M. Hojamberdiev, Y. Xu, B. Cao, J. Wang, and H. Wu, “Hydrothermal synthesis and magnetic properties of gadolinium-doped CoFe2O4 nanoparticles,” J. Magn. Magn. Mater. 323, 133-137 (2011). https://doi.org/10.1016/j.jmmm.2010.08.048
A. Goldman, Modern Ferrite Technology, 2nd ed. (Springer, Pittsburgh, 2006).
V. Awati, K. Badave, and D. Bobade, “Effect of Tb3+ substitution on structural, optical and magnetic properties of NiCuZnFe2O4 prepared by sol-gel route,” Indian J. of Physics, 96(1), 89–101 (2022). https://doi.org/10.1007/s12648-020-01955-5
Copyright (c) 2024 Sanchita V. Chavan, Vyankati R. Jadhav, Sunanda H. Pisal, Ramesh B. Bhise, Mahendra S. Shinde, Vishal H. Goswami, Pradip B. Sarawade
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).