Investigation of Structural, Magnetic and Optical Properties for Dysprosium Doped Zinc Nanoferrites by Sol-Gel Autocombution Techniques

  • Sanchita V. Chavan PG Department of Physics, PDEA’s Annasaheb Magar College, Hadpsar, Pune-28, MS, India
  • Vyankati R. Jadhav PG Department of Physics, PDEA’s Annasaheb Magar College, Hadpsar, Pune-28, MS, India.
  • Sunanda H. Pisal PG Department of Physics, RSS’s S. M. Joshi College, Hadpsar, Pune, MS, India
  • Ramesh B. Bhise PG Department of Physics, Balasaheb Jadhav Arts, Commerce and Science College, Ale (Junnar), Pune, MS, India
  • Mahendra S. Shinde Department of Physics, M.J.M. Arts, Commerce and Science College Karanjali (Peth) Nashik-422 208.(MH), India. https://orcid.org/0000-0001-9141-5049
  • Vishal H. Goswami Department of Physics, Chikitsak Samuha's Sir Sitaram and Lady Shantabai Patkar College of Arts & Science and V. P. Varde College of Commerce & Economics. Goregaon West, Mumbai, Maharashtra, India https://orcid.org/0000-0001-9782-2737
  • Pradip B. Sarawade Department of Physics, University of Mumbai, Kalina, Mumbai, India
Keywords: Autocombustion technique, VSM technique, FT-IR spectroscopy, UV-Visible Spectroscopy, XRD method

Abstract

Using the auto combustion sol-gel method, nanoferrite crystalline aligns of Dy3+ replaced Zn-Fe spinel ferrite with the chemical formula DyxZn1-xFe2-xO4 (x= 0.00, 0.05) were successfully synthesized. In this process, citric acid was utilized as energy (fuel) in a 3:1 ratio to metal nitrate. Using XRD and FT-IR, the crystal structure and phase of dysprosium zinc was examined. Using the XRD method, the crystal size, lattice constant, cation distribution, and porosity were ascertained. FT-IR spectroscopy is used to infer structural study and the redistribution of cations between octahederal (A) and tetrahederal (B) site of Zn material. According to morphological research, the temperature during sintering is what causes grain to form and grow. Utilizing the Hysteresis Loop Technique, saturation magnetism and magneton number are determined. In Zn-Fe ferrite, the saturation magnetization rises with increasing density x, utilizing the Sol-gel auto-combustion method at a comparatively low temperature. Using nitrate citrate, the nanocrystallite DyxZn1-xFe2-xO4 was created. The combustion process and chemical gelation are unique. Using citric acid as a catalyst, their metal nitrates nanoferrites underwent a successful chemical reaction and were obtained as a dried gel. FT-IR, UV-Visible, VSM and XRD were used to characterize the produced nanoferrite powders. Magnetization and hysteresis were measured using the VSM technique. The FT-IR verifies that the synthesized substance is ferrite. The size of the nanocrystalline ferrite material, DyxZn1-xFe2-xO4, was determined by X-ray using the Scherrer method to be between 16.86 to 12.72 nm average crystallite size. Magnetization and hysteresis were measured using the VSM technique.

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Published
2024-06-01
Cited
How to Cite
Chavan, S. V., Jadhav, V. R., Pisal, S. H., Bhise, R. B., Shinde, M. S., Goswami, V. H., & Sarawade, P. B. (2024). Investigation of Structural, Magnetic and Optical Properties for Dysprosium Doped Zinc Nanoferrites by Sol-Gel Autocombution Techniques. East European Journal of Physics, (2), 315-320. https://doi.org/10.26565/2312-4334-2024-2-36