Forecast of organic matter content in the waters of the Danube river (Kilia)

Keywords: Danube, BOD₅, water quality, organic pollution, forecast, lognormal distribution, monitoring, risk

Abstract

Purpose. To assess and forecast the risk of water quality deterioration in the Danube River within the city of Kiliya based on the biochemical oxygen demand (BOD₅) indicator.

Methods. Statistical analysis methods were applied, including the lognormal distribution to estimate the probabilities of exceeding threshold concentrations, and extrapolation of the trend line to forecast the dynamics of the BOD₅ indicator. Data visualization was performed by constructing graphs for various time intervals.

Results. The comparison between actual and forecasted BOD₅ values showed a satisfactory level of discrepancy (up to 17% for risk assessment and up to 5% for actual values), confirming the effectiveness of the chosen approach even under conditions of irregular monitoring data, while taking into account ecological standards and EU Directive requirements. It was found that the concentration of organic substances in the water at the 10% probability level significantly exceeds the ecologically permissible value of 3 mg/dm³ (according to EU standards) and shows a tendency for gradual increase.

Conclusion. The results of the study confirm the effectiveness of the applied approach to water quality forecasting under conditions of irregular monitoring. The use of the lognormal distribution combined with trend line extrapolation allowed for reliable estimations of both the actual state of the water and the probability of exceeding ecologically hazardous concentrations.

Downloads

Download data is not yet available.

Author Biographies

V. V. Terzeman, Odesa I.I. Mechnikov National University

Postgraduate student of the Department of Environmental Science and Environmental Protection

S. M. Yurasov, Odesa I.I. Mechnikov National University

PhD (Technic), Associate Professor, Associate Professor of the Department of Environmental Science and Environmental Protection

References

Ismail, A.H., & Robescu, L.D. (2019). Assessment of water quality of the Danube river using water quality indices technique. Environmental Engineering and Management Journal, 18(8), 1727-1737. http://dx.doi.org/10.30638/eemj.2019.163

Frincu, R. (2021). Long-Term Trends in Water Quality Indices in the Lower Danube and Tributaries in Romania (1996–2017) International Journal of Environmental Research and Public Health, 18(4), 1665. http://dx.doi.org/10.3390/ijerph18041665

Iticescu, C., Georgescu, L.P., Murariu, G., Topa, C., Timofti, M., Pintilie, V., & Arseni, M. (2019). Lower Danube Water Quality Quantified through WQI and Multivariate Analysis. Water, 11(6):1305. https://doi.org/10.3390/w11061305

Kolisnyk, A., & Pylypiuk, V. (2022). Assessment of Ecological Risk of Surface Water Quality Deterioration in the Sub-basin of the Middle Dnipro within Poltava Region. Problems of Chemistry and Sustainable Development, 4, 61-69. https://doi.org/10.32782/pcsd-2022-4-6 (in Ukrainian)

Bezsonnyi, V. L., Tretyakov, O. V., Nekos, A. N., & Chistov, Ye. V. (2024). Prediction of oxygen regime indicators in Danube river. Man and Environment. Issues of Neoecology, (42), 6-23. https://doi.org/10.26565/1992-4224-2024-42-01 (in Ukrainian)

Pekarova, P., Onderka, M., Pekar, J., Roncak, P., & Miklanek, P. (2009). Prediction of Water Quality in the Danube River Under extreme Hydrological and Temperature Conditions. Journal of Hydrology and Hydromechanics, 57, 3-15. https://doi.org/10.2478/v10098-009-0001-5

Salvai, A., Grabic, J., Zemunac, R., & Antonic, N. (2022). Trend Analysis of Water Quality Parameters in the Middle Part of the Danube Flow in Serbia, Ecological Chemistry and Engineering S, 29(1), 51-63. https://doi.org/10.2478/eces-2022-0006

Georgescu, L., Moldovanu, S., Iticescu, C., & Calmuc, M. (2023). Assessing and forecasting water quality in the Danube River by using neural network approaches. The Science of the Total Environment. 879. https://doi.org/10.1016/j.scitotenv.2023.162998

Vaikunta, Rao, Pravin, R.K. Shirsagar, Kuan Tak Tan, Sivaneasan Bala Krishnan, Shrikant V. Sonekar & Sayali Zade (2025). The Assessment of Water Quality Forecasting Using AI-Based ML Algorithms. Metallurgical and Materials Engineering, 31(4), 942–961. https://doi.org/10.63278/1539

Ooi, K.S., Chen, Z.Y., Poh, P. E., & Cui, J. (2022. BOD5 prediction using machine learning methods. Water Supply, 22 (1) 1168–1183. https://doi.org/10.2166/ws.2021.202

Kim, S., Alizamir, M., Seo, Y., Heddam, S., & Chung, I. (2022). Estimating the incubated river water quality indicator based on machine learning and deep learning paradigms: BOD5 Prediction. Mathematical Biosciences and Engineering, 19(12), 12744-12773. https://doi.org/10.3934/mbe.2022595

Water Code of Ukraine. Code of Ukraine; Law, Code dated 06.06.1995 No. 213/95-VR. Retrieved from https://zakon.rada.gov.ua/laws/show/213/95-%D0%B2%D1%80#Text (Accessed: 15.05.2025)( in Ukrainian).

On Environmental Protection. Law of Ukraine dated 25.06.1991 No. 1264-XII. Retrieved from https://zakon.rada.gov.ua/laws/show/1264-12#Text (Accessed: 15.05.2025) (in Ukrainian).

On Approval of the State Sanitary Norms and Rules "Hygienic Requirements for Drinking Water Intended for Human Consumption" (DSanPiN 2.2.4-171-10). Ministry of Health of Ukraine; Order, Norms, Rules dated 12.05.2010 No. 400. Retrieved from https://zakon.rada.gov.ua/laws/show/z0452-10#Text (Accessed: 15.05.2025) (in Ukrainian).

Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 Establishing a Framework for Community Action in the Field of Water Policy. Retrieved from https://zakon.rada.gov.ua/laws/show/994_962#Text (Accessed: 15.05.2025) (in Ukrainian)

COUNCIL DIRECTIVE 75/440/EEC of 16 June 1975 concerning the quality required of surface water intended for the abstraction of drinking water in the Member States. Retrieved from: https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:31975L0440&from=en

COUNCIL DIRECTIVE 76/160/EEC of 8 December 1975 concerning the quality of bathing water. Retrieved from: http://river.bio.auth.gr/wp-content/uploads/2016/09/Directive-76-160-EEC-Bathing-Water.pdf

COUNCIL DIRECTIVE 78/659/EEC of 18 July 1978 on the quality of fresh waters needing protection or improvement in order to support fish life. Retrieved from: http://www.cawater-info.net/water_quality_in_ca/files/eu_659-78.pdf

COUNCIL DIRECTIVE 98/83/EC of 3 November 1998 on the quality of water intended for human consumption. Retrieved from: https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:31998L0083&from=EN

Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy. Retrieved from: https://eur-lex.europa.eu/resource.html?uri=cellar:5c835afb-2ec6-4577-bdf8-756d3d694eeb.0004.02/DOC_1&format=PDF

DIRECTIVE (EU) 2020/2184 of the European Parliament and of the Council of 16 December 2020 on the quality of water intended for human consumption. Retrieved from: https://eur-lex.europa.eu/eli/dir/2020/2184/oj

Yurasov, S.M., & Terzemam, V.V. (2023). Water Quality: Assessment, Variability, Forecasting, Regulation. LAP LAMBERT Academic Publishing, Retrieved from https://www.morebooks.shop/shop-ui/shop/product/9786206846079 (Accessed: 09.10.2024) (in Ukrainian).

Yurasov, S. M., Karaulov, V.D., & Terzeman, V.V. (2025). Improved assessment and forecasting of irrigation water quality. Man and Environment. Issues of Neoecology, (43), 33-46. https://doi.org/10.26565/1992-4224-2025-43-03 (in Ukrainian)

Published
2025-06-14
How to Cite
Terzeman, V. V., & Yurasov, S. M. (2025). Forecast of organic matter content in the waters of the Danube river (Kilia). Visnyk of V. N. Karazin Kharkiv National University. Series Еcоlogy, (32), 61-70. https://doi.org/10.26565/1992-4259-2025-32-04