Effect of organomodified laponite on the structure of polymeric nanocomposites in bulk and thin films

  • Е. А. Лисенков Миколаївський національний університет ім. В.О. Сухомлинського
  • С. І. Бохван Інститут хімії високомолекулярних сполук НАН України
  • В. В. Клепко Інститут хімії високомолекулярних сполук НАН України
Keywords: polymer nanocomposites, degree of crystallinity, laponite, polymer electrolyte, thin films

Abstract

The research of the structure of polymer nanocomposites and nanocomposite polymer electrolytes based on polyethylene glycol (PEG) and organomodified laponite in bulk and thin films is done using X-ray diffraction analysis. It is shown that the structure of systems based on PEG is essentially dependent on the content of the nanofiller and the type of substrate on which the film was formed. It was found that the degree of crystallinity of polymer electrolytes based on PEG has an extreme dependence on the content of the filler.

Downloads

Download data is not yet available.

References

Puggal S., Dhall N., Singh N., Litt M. S. A Review on Polymer Nanocomposites: Synthesis, Characterization and Mechanical Properties // Indian Journal of Science and Technology. — 2016. — Vol. 9, No. 4. — P. 1–6.

Zhan C., Yu G., Lu Y., Wang L. Wujcik E., Wei S. Conductive polymer nanocomposites: a critical review of modern advanced devices // J. Mater. Chem. C. — 2017. — Vol. 5. — P. 1569-1585.

Dundigalla A., Lin-Gibson S., Ferreiro V., Malwitz M. M., Schmidt G. Unusual multilayered structures in poly(ethylene oxide) / laponite nanocomposite films // Macromol. Rapid. Commun. — 2005. — Vol. 26. — P. 143–149.

Bauhofer W., Kovacs J. Z. A review and analysis of electrical percolation in carbon nanotube polymer composites // Compos. Sci. Technol. — 2009. — Vol. 69. — P. 1486–1498.

Lysenkov E. A., Lebovka N. I., Yakovlev Y. V., Klepko V. V., Pivovarova N. S. Percolation Behaviour of Polypropylene Glycol Filled with Multiwalled Carbon Nanotubes and Laponite // Compos. Sci. and Techn. — 2012. — Vol. 72. — P. 1191–1195.

Valapa R. B., Loganathan S., Pugazhenthi G., Thomas S., Varghese T. O. An Overview of Polymer-Clay Nanocomposites, In ClayPolymer Nanocomposites, London, New York: Elsevier, 2017. — P. 29–81.

Pavlidou S., Papaspyrides C. D. A Review on Polymer-Layered Silicate Nanocomposites // Progress in Polymer Science. — 2008. — Vol. 33. — P. 1119–1198.

Paiva L. B., Morales A. R., Diaz F. V. Organoclays: Properties, preparation and applications // Applied Clay Science. — 2008. — Vol. 42. — P. 8–24.

Wassel E., Es-Souni M., Berger N., Schopf D., Dietze M., Solterbeck C. -H., Es-Souni M. Nanocomposite Films of Laponite / PEGGrafted Polymers and Polymer Brushes with Nonfouling Properties // Langmuir. — 2017. — Vol. 33, No. 27. — P. 6739–6750.

Piao S. H., Kwon S. H., Choi H. J. StimuliResponsive Polymer-Clay Nanocomposites under Electric Fields // Materials. — 2016. — Vol. 9. — P. 52–61.

Lipatov Yu. S., Shilov V. V., Gomza Yu. P., Kruglyak N. E. Rentgenograficheskie metody izucheniya polimernyh sistem. — Kiev: Naukova dumka, 1982. — 296 p.

Andreev A. V. Rentgenovskaya optika poverhnosti. Otrazhenie i difrakciya pri skol’zyaschih uglah padeniya // PTE. — 1985. — Vol. 145, No. 1. — P. 113–136.

Shtypulyak N. I., Yakimov I. I., Litvincev V. V. Rentgenodifraktometricheskie issledovaniya struktury pripoverhnostnyh sloev v parallel’nyh skol’zyaschih luchah // PTE. — 1988. — Vol. 148, No. 5. — P. 181–184.

Gomza Yu. P., Klepko V. V., Nesіn S. D., Lisenkov E. A., Kunic’kij Yu. A., Barabash M. Yu., Homenko L. G. Rentgenografіchnі doslіdzhennya blizhn’oї vporyadkovanostі nadtonkih plіvok // Nanosistemi, nanomaterіali, nanotehnologії. — 2009. — Vol. 7, No. 2. — P. 411–419.

Lisenkov E. A., Gomza Yu. P., Klepko V. V. Vpliv anіzometrichnih nanonapovnyuvachіv na strukturu ta provіdnіst’ PEG1000/LiClO4 v ob’єmі ta tonkih plіvkah // Polіmernij zhurnal. — 2010. — Vol. 32, No. 3. — P. 123– 128.

Chen H. W., Chang F. C. The novelpolymer electrolyte nanocomposite composed of poly(ethylene oxide), lithium triflate and mineral clay // Polymer. — 2001. —

Vol. 42. — P. 9763–9769.

Published
2017-12-14
How to Cite
Лисенков, Е. А., Бохван, С. І., & Клепко, В. В. (2017). Effect of organomodified laponite on the structure of polymeric nanocomposites in bulk and thin films. Journal of Surface Physics and Engineering, 2(4), 223-230. Retrieved from https://periodicals.karazin.ua/pse/article/view/11252

Most read articles by the same author(s)