A 31% Efficient CIGS-Based Solar Cell Using Spiro Material as a Buffer Layer: Numerical Simulation

  • Mohamed Hamdaoui Optoélectronique et Techniques Energétiques Appliquées, Department of Engineering Sciences, Faculty of sciences and techniques, Moulay Ismaïl University of Meknès, Boutalamine, Errachidia, Morocco https://orcid.org/0009-0008-9063-0984
  • Lhoussayne Et-taya Optoélectronique et Techniques Energétiques Appliquées, Department of Engineering Sciences, Faculty of sciences and techniques, Moulay Ismaïl University of Meknès, Boutalamine, Errachidia, Morocco https://orcid.org/0000-0002-9815-3667
  • Abdellah Benami Optoélectronique et Techniques Energétiques Appliquées, Department of Engineering Sciences, Faculty of sciences and techniques, Moulay Ismaïl University of Meknès, Boutalamine, Errachidia, Morocco https://orcid.org/0000-0001-5516-5660
  • Malika Ouhadou Optoélectronique et Techniques Energétiques Appliquées, Department of Engineering Sciences, Faculty of sciences and techniques, Moulay Ismaïl University of Meknès, Boutalamine, Errachidia, Morocco https://orcid.org/0000-0002-9751-2381
  • Abderrahman El Boukili Physique Moderne, Rayonnement et Applications, Department of Engineering Sciences, Faculty of sciences and techniques, Moulay Ismaïl University of Meknès, Boutalamine Errachidia, Morocco https://orcid.org/0000-0002-3277-9640
  • Jaouad Fosh Électronique et Systèmes Intelligents, Optoelectronics and Applied Energy Technics (OAET), Department of Engineering Sciences, Faculty of sciences and techniques, Moulay Ismaïl University of Meknès, Boutalamine Errachidia, Morocco https://orcid.org/0000-0002-8509-6130
Keywords: SCAPS, Operating temperature, Thickness, Work function, Parameter of solar cells

Abstract

This study investigates the potential boost of (Cu(In,Ga)Se2) based solar cells through numerical simulations using SCAPS-1D software to optimize their performance. Various parameters were analyzed, including the thickness, acceptor concentration, and band gap of the CIGSe active layer, as well as the donor concentration and thickness of the ZrS2 buffer layer. The impact of operating temperature was also considered. The optimized output characteristics of the proposed cell design include a VOC of 1.13V, JSC of 32.61mA/cm², FF of 89.12, and a PCE of 32.91. These findings can aid in advancing the development of high-efficiency CIGSe-based thin-film solar cells.

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References

A. Azmand and A.H. Kafashan, “Al-doped ZnS thin films: Physical and electrochemical characterizations,” J. Alloys Compd. 779, 301-313 (2019). https://doi.org/10.1016/j.jallcom.2018.11.268

R.N. Bhattacharya, M.-K. Oh and Y. Kim, “CIGS-based solar cells prepared from electrodeposited precursor films,” Sol. Energy Mater. Sol. Cells, 98, 198–202 (2012). https://doi.org/10.1016/j.solmat.2011.10.026

Qi Chen, et al., “Spiro-OMeTAD doped with cumene hydroperoxide for perovskite solar cells,” Electrochemistry Communications, 126, 107020 (2021). https://doi.org/10.1016/j.elecom.2021.107020

H. Kafashan and A. Bahrami, “CIGS solar cells using ZrS2 as buffer layer: Numerical simulation,” Optik - International Journal for Light and Electron Optics, 298, 171594 (2024). https://doi.org/10.1016/j.ijleo.2023.171594

P. Ganesan, et al., “A simple spiro-type hole transporting material for efficient perovskite solar cells,” Energy. Environ. Sci. 8(7), 1986–1991 (2015). https://doi.org/10.1039/C4EE03773A

M. Al-Hattab, et al., “Numerical simulation of a new heterostructure CIGS/GaSe solar cell system using SCAPS-1D software,” Sol. Energy, 227, 13–22 (2021). https://doi.org/10.1016/j.solener.2021.08.084

M. Moustafa, T. Al Zoubi and S. Yasin, “Exploration of CZTS-based solar using the ZrS2 as a novel buffer layer by SCAPS simulation,” Opt. Mater. 124, 112001 (2022). https://doi.org/10.1016/j.optmat.2022.112001

M. Ameri, E. Mohajerani, M. Ghafarkani, N. Safari and S.A. Alavi, “The investigation of the unseen interrelationship of grain size, ionic defects, device physics and performance of perovskite solar cells,” J. Phys. D Appl. Phys. 52, 125501 (2019). https://doi.org/10.1088/1361-6463/AAFEA9

Y. Raoui, H. Ez-Zahraouy, N. Tahiri, O. El Bounagui, S. Ahmad and S. Kazim, “Performance analysis of MAPbI (3) based perovskite solar cells employing diverse charge selective contacts: Simulation study,” Sol. Energy, 193, 948–955 (2019). https://doi.org/10.1016/j.solener.2019.10.009

S. Karthick, J. Boucle and S. Velumani, “Effect of bismuth iodide (BiI3) interfacial layer with different HTL’s in FAPI based perovskite solar cell-SCAPS-1D study,” Sol. Energy, 218, 157–168 (2021). https://doi.org/10.1016/j.solener.2021.02.041

A. Hima, N. Lakhdar and A. Saadoune, “Effect of Electron Transporting Layer on Power Conversion Efficiency of Perovskite-Based Solar Cell: Comparative Study,” Journal of Nano- and Electronic Physics, 11, 01026 (2019). https://doi.org/10.21272/jnep.11(1).01026

D. Valencia, J. Conde, A. Ashok, C.A. Meza-Avendaño, H. Vilchis and S. Velumani, “Optimization of Cu(In, Ga)Se2 (CIGSe) thin film solar cells parameters through numerical simulationand experimental study,” Sol. Energy, 224, 298-308 (2021). https://doi.org/10.1016/j.solener.2021.05.075

H. Aissat, H. Arbouz and J.P. Vilcot, “Optimization and improvement of a front graded bandgap CuInGaSe2 solar cell,”, Solar Energy Materials and Solar Cells, 180, 381-385 (2018). https://doi.org/10.1016/j.solmat.2017.09.017

A. Belghachi and N. Limam, “Effect of the absorber layer band-gap on CIGS solar cell,” Chinese Journal of Physics, 55(4), 1127-1134 (2017). https://doi.org/10.1016/j.cjph.2017.01.011

S. Bechlaghem, B. Zebentout and Z. Benamara, “The major influence of the conduction-bandoffset on Zn (O, S)/CuIn0.7Ga0.3Se2 solar cells,” Results in Physics, 10, 650-654 (2018). https://doi.org/10.1016/j.rinp.2018.07.006

L. Et-taya, T. Ouslimane and A. Benami, “'Numerical Simulation of Third-Generation Solar Cells Based on Kesterite CZTSSe Using SCAPS-1D,” in: Proceedings of the 3rd International Conference on Electronic Engineering and Renewable Energy Systems. ICEERE, 2022. Lecture Notes in Electrical Engineering, editet by H. Bekkay, A. Mellit, A. Gagliano, A. Rabhi, and A. Koulali, vol. 954. (Springer, Singapore, 2022). http://dx.doi.org/10.1007/978-981-19-6223-3_31

Y. Osman, M. Fedawy, M. Abaza and M.H. Aly, “Optimized CIGS based solar cell towards an efficient solar cell: impact of layers thickness and doping”, Optical and Quantum Electronics, 53, 245 (2021). https://doi.org/10.1007/s11082-021-02873-4

M. Abdelfatah, et al., “Fabrication and characterization of low cost Cu2O/ZnO: Al solar cells for sustainable photovoltaics with earth abundant materials,” Sol. Energy Mater. Sol. Cells, 145, 454–461 (2016). https://doi.org/10.1016/j.solmat.2015.11.015

H. Kafashan and A. Bahrami, “CIGS solar cells using ZrS2 as buffer layer: Numerical simulation,” Optik, 298, 71594 (2024). https://doi.org/10.1016/j.ijleo.2023.171594

T. AlZoubi and M. Moustafa, “Numerical optimization of absorber and CdS buffer layers in CIGS solar cells using SCAPS,” International Journal of Smart Grid and Clean Energy, 8, 291-298 (2019). https://doi.org/10.12720/sgce.8.3.291-298

L. Et-Taya, A. El Khalfi, M. Ouhadou, A. El Boukili, Md.F. Rahman and A. Benami, “Design and simulation of a new kesterite solar cell structure with and without a perovskite back surface field layer to exceed 32% efficiency,” Physica Scripta, 99(5), 055922 (2024). https://doi.org/10.1088/1402-4896/ad3684

L Et-taya, T. Ouslimane and A. Benami, “Numerical analysis of earth-abundant Cu2ZnSn(SxSe1-x)4 solar cells based on Spectroscopic Ellipsometry results by using SCAPS-1D,” Solar Energy, 201, 827-835 (2020). https://doi.org/10.1016/j.solener.2020.03.070

X. Liu, B. Zheng, L. Shi, et al., « Perovskite solar cells based on spiro-OMeTAD stabilized with an alkylthiol additive,” Nat. Photon. 17, 96–105 (2023). https://doi.org/10.1038/s41566-022-01111-x

C. Lin, G. Liu, X. Xi, L. Wang, Q. Wang, Q. Sun, M. Li, et al., “The Investigation of the Influence of a Cu2O Buffer Layer on Hole Transport Layers in MAPbI3-Based Perovskite Solar Cells,” Materials, 15, 8142 (2022). https://doi.org/10.3390/ma15228142

S. Rabhi, et al., “The impact of CBz-PAI interlayer in various HTL-based flexible perovskite solar cells: A drift-diffusion numerical study”, Heliyon, 10(10), e31138 (2024). https://doi.org/10.1016/j.heliyon.2024.e31138

H.S. Najafabadi, M.A. Meier and G.A. Hallock, “Charge carrier transport and electrical response by driving band gap modulation in semiconductors,” Applied Materials Today, 29, 101608 (2022). https://doi.org/10.1016/j.apmt.2022.101608

L.V.T. Merino, et al., “Impact of the valence band energy alignment at the hole-collecting interface on the photostability of wide band-gap perovskite solar cells”, Joule, 8(9), 2585-2606 (2024). https://doi.org/10.1016/j.joule.2024.06.017

A. Chen and K. Zhu, “Computer simulation of a-Si/c-Si heterojunction solar cell with high conversion efficiency,”. Sol. Energy, 86, 393–397 (2012). https://doi.org/10.1016/j.solener.2011.10.015

Rihana, S.F. Ahmed and M. Khalid, “Simulation of CIGS based solar cells with SnO2 window layer using SCAPS-1D,” in: 2019 International Conference on Power Electronics, Control and Automation (ICPECA), (New Delhi, India, 2019), pp. 1-4. https://doi.org/10.1109/ICPECA47973.2019.8975461

H. Heriche, Z. Rouabah and N. Bouarissa, “New ultra-thin CIGS structure solar cells using SCAPS simulation program,” International Journal of Hydrogen Energy. 42, 9524-9532 (2017). https://doi.org/10.1016/j.ijhydene.2017.02.099

M. Hamdaoui, L. Et-Taya, J. Foshi, N. Mansour and A. Benami, “Enhancement of the performance of solar cells based-CIGSe by using SCAPS-1D,” in: 2024 International Conference on Circuit, Systems and Communication (ICCSC), (Fes, Morocco, 2024), pp. 1-4, https://doi.org/10.1109/ICCSC62074.2024.10617204

Published
2025-09-08
Cited
How to Cite
Hamdaoui, M., Et-taya, L., Benami, A., Ouhadou, M., El Boukili, A., & Fosh, J. (2025). A 31% Efficient CIGS-Based Solar Cell Using Spiro Material as a Buffer Layer: Numerical Simulation. East European Journal of Physics, (3), 466-475. https://doi.org/10.26565/2312-4334-2025-3-51