Thermodynamic Properties of Mn-Doped Diluted Magnetic Semiconductor Superlattices
Abstract
This work investigates the thermodynamic properties of a two-dimensional electron gas in manganese-doped diluted magnetic semiconductor superlattices, with particular emphasis on the chemical potential. Within the grand canonical formalism, a general expression for the chemical potential is derived that is valid for both degenerate and nondegenerate cases. In the nondegenerate limit, the chemical potential decreases with increasing temperature and exhibits a logarithmic dependence on carrier density; the temperature sensitivity is most pronounced at low carrier concentrations, where entropic effects dominate. In the degenerate regime, Landau quantization leads to a characteristic stepwise oscillatory dependence of the chemical potential on the applied magnetic field. The influence of the exchange interaction is analyzed in two limiting cases: in the weak-coupling limit, the correction to the chemical potential is linear in the concentration and exchange constant, whereas in the strong-coupling limit, the system approaches complete spin polarization with carriers confined predominantly to a single spin channel. The exchange interaction introduces an additional spin-dependent contribution described by the Brillouin function, resulting in the most pronounced modifications at low temperatures and in strong magnetic fields.
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References
J. Kossut, and J.A. Gaj, Introduction to the physics of diluted magnetic semiconductors, (Springer, Berlin, Heidelberg, 2010), p. 469, https://doi.org/10.1007/978-3-642-15856-8
P. Kacman, “Spin interactions in diluted magnetic semiconductors and magnetic semiconductor structures”, Semiconductor Science and Technology, 16(4), R25-R39 (2001). https://doi.org/10.1088/0268-1242/16/4/201
A. Gupta, R. Zhang, P. Kumar, V. Kumar, and A. Kumar, “Nano-structured dilute magnetic semiconductors for efficient spintronics at room temperature”, Magnetochemistry, 6(1), 1-22 (2020). https://doi.org/10.3390/magnetochemistry6010015
A.M. Babanli, and B.G. Ibragimov, “Magnetic moment of electrons in diluted magnetic semiconductor quantum ring”, in: Proceedings of the 6th International conference on Control and Optimization with Industrial Applications (COIA, Baku, 2018), pp.122-124.
Berry Habte Dulla, “Thermodynamic properties of diluted magnetic semiconductors using Heisenberg spin model in 3D”, Journal of Applied Physical Science International, 2(3), 101-106 (2015). https://ikprress.org/index.php/JAPSI/article/view/2844
J. Ricardo de Sousa, and N.S. Branco, “Two-dimensional quantum spin -½ Heisenberg model with competing interactions”, Physical Review B, 72(13), 134421 (2005). https://doi.org/10.1103/PhysRevB.72.134421
R.N. Bhatt, M. Berciu, M.P. Kennett, and X.Wan, “Diluted magnetic semiconductors in the low carrier density regime”, Journal of Superconductivity, 15(1), 71-83 (2002), https://doi.org/10.1023/A:1014031327996
W. Zawadzki, “Theory of optical transitions in inversion layers of narrow-gap semiconductors”, Journal of Physics C: Solid State Physics, 16(1), 229-240 (1983). https://doi.org/10.1088/0022-3719/16/1/025
T. Dietl, and H. Ohno, “Dilute ferromagnetic semiconductors: Physics and spintronic structures”, Reviews of Modern Physics, 86(1), 187-251 (2014). https://doi.org/10.1103/RevModPhys.86.187
T. Jungwirth, J. Sinova, J. Mašek, J. Kučera, and A.H. MacDonald, “Theory of ferromagnetic (III,Mn)V semiconductors”, Reviews of Modern Physics, 78(3), 809-864 (2006). https://doi.org/10.1103/RevModPhys.78.809
G. Bastard, Wave Mechanics Applied to Semiconductor Heterostructures, (Monographs of Physics (Les Editions de Physique)), (Wiley-Interscience Publishing, Paris, 1991), p. 357.
D.R. Yakovlev, A. Keller, et al. “Kinetic exchange between the conduction band electrons and magnetic ions in quantum-confined structures”, Physical Review Letters, 83(7), 1431-1434 (1999). https://doi.org/10.1103/PhysRevLett.83.1431
H. Ohno, “Making nonmagnetic semiconductors ferromagnetic”, Science, 281(5379), 951-956 (1998). https://doi.org/10.1126/science.281.5379.951
A.H. MacDonald, P. Schiffer, and N. Samarth, “Ferromagnetic semiconductors: moving beyond (Ga,Mn)As”, Nature Materials, 4(3), 195-202 (2005). https://doi.org/10.1038/nmat1325
T. Dietl, H. Ohno, F. Matsukura, J. Cibert, and D. Ferrand, “Zener model description of ferromagnetism in zinc-blende magnetic semiconductors”, Science, 287(5455), 1019-1022 (2000). https://doi.org/10.1126/science.287.5455.1019
S. Lee, S. Chung, H. Lee, X. Liu, M. Dobrowolska, and J.K. Furdyna, “Interlayer exchange coupling in (Ga,Mn)As ferromagnetic semiconductor multilayer systems”, Journal of Semiconductors, 40(8), 081503 (2019). https://doi.org/10.1088/1674-4926/40/8/081503
K. Ando, H. Saito, Z. Jin, T. Fukumura, M. Kawasaki, Y. Matsumoto, and H. Koinuma, “Magneto-optical properties of ZnO-based diluted magnetic semiconductors”, Journal of Applied Physics, 89(11), 7284-7286 (2001). https://doi.org/10.1063/1.1356035
D.D. Awschalom, and M.E. Flatté, “Challenges for semiconductor spintronics”, Nature Physics, 3, 153-159 (2007). https://doi.org/10.1038/nphys551
I. Žutić, J. Fabian, and S. Das Sarma, “Spintronics: Fundamentals and applications”, Reviews of Modern Physics, 76(2), 323-410 (2004). https://doi.org/10.1103/RevModPhys.76.323
В.M. Аskerov, and S.R. Figarova, Thermodynamics, Gibbs Method and Statistical Physics of Electron Gases, (Springer, Berlin, Heidelberg, 2010), p. 374. https://doi.org/10.1007/978-3-642-03171-7
S.R. Figarova, M.M. Mahmudov, and R.Y. Damirov, “Magnetization of diluted magnetic semiconductor II type superlattices with impurities Mn (manganese) ions”, Journal of Baku Engineering University: PHYSICS, 8(1), 9-15 (2024). https://doi.org/10.30546/09081.2024.101.5002
M.M. Mahmudov, and R.Y. Damirov, “Entropy of diluted magnetic semiconductor superlattices with impurities Mn ions”, Baku State University: Journal of Physics and Space Sciences, 2(2), 9-16 (2025). https://doi.org/10.30546/209501.101.2025.2.02.03
Copyright (c) 2026 Mehdi M. Mahmudov, Ragib Y. Damirov, Naila S. Sardarova, Arzu M. Ahmadova

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