Effect of Impurity and Radiation Defects on Anisotropy of Yb-Doped GaS Single Crystal

  • R.S. Madatov Institute of Radiation Problems, Ministry of Science and Education Republic of Azerbaijan, B. Vagabzadeh street 9, АZ 1143, Baku, Azerbaijan; Department of Applied and General Physics, National Aviation Academy, Baku, Azerbaijan https://orcid.org/0000-0003-2420-2654
  • T.B. Tagiev Institute of Radiation Problems, Ministry of Science and Education Republic of Azerbaijan, Baku, Azerbaijan https://orcid.org/0009-0009-9890-8554
  • A.Sh. Khaligzadeh Institute of Radiation Problems, Ministry of Science and Education Republic of Azerbaijan, Baku, Azerbaijan https://orcid.org/0009-0001-6325-0440
  • R.M. Mamishova Institute of Radiation Problems, Ministry of Science and Education Republic of Azerbaijan, Baku, Azerbaijan; cAzerbaijan University of Architecture and Construction, Baku, Azerbaijan https://orcid.org/0000-0002-1760-8384
Keywords: Anisotropy, Defects, Impurity atom, Electrical conductivity, Activation, Thermal annealing

Abstract

The effect of γ-quanta on the anisotropy of GaS layered single crystal, pure and alloyed with 0.1at% Yb, has been studied at a temperature range of 125-300K. Since the difference between the ionic radius of the Yb-atom and the ionic radius of the component atoms is relatively small when the studied GaS monocrystal is added with itterbium ions, the additive atom is likely to be located both inside the layers (replacing the Ga atom or between nodes) and in interlayer space. The location of impurity atoms and radiation defects in the interlayer region of the layered GaS (Yb) crystal weakens the anisotropic properties of the crystals, and the location inside the layer strengthens them. The mechanism of current flow in high electric fields follows the Frenkel model, regardless of the nature of the impurity atom.

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References

A.Z. Abasova, R.S. Madatov, and V.I. Stafeev, Radiation-stimulated processes in chalcogenide structures, (ELM, Baku, Azerbaijan, 2010).

G. Micocci, R. Rella, P. Siciliano, and A. Tepore, “Investigation of electronic properties of gallium sulfide single crystals grown by iodine chemical transport,” Journal of Applied Physics, 68(1), 138-142 (1990). https://doi.org/10.1063/1.347105

B.Q. Tagiev, A.R. Hajiev, and R.S. Madatov, “On the anisotropy of layered semiconductors GaSe and GaTe,” J. Physics of the Academy of Sciences of Azerbaijan, 3(3), 84-87 (1997). http://physics.gov.az/Dom/1997/v3article/F19970103_24.pdf (in Russian)

R.H. Al-Orainy, “Growth, Characterization and Electrical Anisotropy in Layered Chalcogenide Gallium Monosulphide Single Crystals,” JKAU: Sci. 22(2), 3-12 (2010). https://www.kau.edu.sa/Files/363/Researches/64767_36125.pdf

V. Augelli, V. Augelli, C. Manfredotti, and R. Murri, “Resistivity anisotropy in p-type GaSe,” Nuovo Cim. 47(1), 101 103 (1978). https://doi.org/10.1007/BF02894621

P.I. Savitskii, I.V. Mintyanskii, and Z.D. Kovalyuk, “Annealing Effect on Conductivity Anisotropy in Indium Selenide Single Crystals,” Physics status solidi (a), 155(2), 451-460 (1996). https://doi.org/10.1002/pssa.2211550218

R. Madatov, A. Najafov, A. Alakbarov, T. Tagiev, and A. Khaliqzadeh, “Features of electrical and photolectric properties of GaS(Yb) monocrystals,” Journal of Physical Sciences, 74(9), 1-5 (2019). https://doi.org/10.1515/zna-2018-0475

R.S. Madatov, R.M. Mamishova, M.A. Mamedov, J. Ismayılov and U.V. Faradjova, “Electrophysical properties of Pb1−XMnXSe epitaxial films irradiated by γ-quanta,” Turk Journal of Physics, 44, 214–221 (2020). https://doi.org/10.3906/fiz-1906-14

R.S. Madatov, T.B. Tagiev, and A.Sh. Khalygzade, “Features of the defecation mechanism in layered GaS(Yb) single crystals under irradiation with low doses of γ-quanta,” Trans. Az. Nat. Acad. Sci., Physics and Astronomy, 38(5), 90-96 (2018). http://physics.gov.az/Transactions/2018/journal2018(5).pdf (in Russian)

A.S. Khaliqzadeh, “Processes Happened in the Photoelectrical Processes of GaS Monocrystal Alloyed Yb and Irradiated by γ- Rays,” Works of Young Scientists, 4(1), 37-40 (2018). https://gencalimler.az/uploads/Genc_Tedqiqatci_N2_2018.pdf (in Azerbaijan)

R. Madatov, R. Mamishova, A. Abasova, and S. Alahverdiyev, “Diferential-thermal analysis and a microscopic study of the effect of ℽ-radiation on CuTlSe2 single crystal,” International Journal of Modern Physics B, 37(30), 2350265 (2023). https://doi.org/10.1142/S021797922350265X

R.S. Madatov, R.M. Mamishova, and G.B. Baylarov, “Characteristics of current injection in the narrow -band p-CuTlS single crystal,” Applied Physics A, 127, 364 (2021). https://doi.org/10.1007/s00339-021-04515-8

R.S. Madatov, and R.M. Mamishova, “A study of the effect of γ-radiation on the current-carrying mechanism in the p-CuTlS2 single crystal,” Modern Physics Letters B, 38(30), 2450295 (2024). https://doi.org/10.1142/S0217984924502956

R.S. Madatov, T.B. Tagiev, S.A. Abushev, Sh.P. Shekili, and A.R. Mobili, “Optical and Photoelectric Properties of Gamma-Irradiated GaS:Er+3 Layered Crystals,” Inorganic Materials, 44(4), 333–336 (2008). https://doi.org/10.1134/S002016850804002X

Y.Gutiérrez, D. Juan, S. Dicorato, G. Santos, M. Duwe, P.H. Thiesen, M.M. Giangregorio, et al., “Layered gallium sulfide optical properties from monolayer to CVD crystalline thin films,” Optics Express, 30(15), 27609-27622 (2022). https://doi.org/10.1364/OE.459815

J. Suh, “Point Defects in Two-Dimensional Layered Semiconductors: Physics and Its Applications,” PhD Thesis, University of California, Berkeley, (2015).

K. Xu, L. Yin, Y. Huang, T.A. Shifa, J. Chu, F. Wang, R. Cheng, et al., “Synthesis, Properties and applications of 2D layered MIIIXVI (M = Ga, In; X = S, Se, Te) materials,” Nanoscale, 8, 16802-16818 (2016). https://doi.org/10.1039/C6NR05976G

Published
2025-03-03
Cited
How to Cite
Madatov, R., Tagiev, T., Khaligzadeh, A., & Mamishova, R. (2025). Effect of Impurity and Radiation Defects on Anisotropy of Yb-Doped GaS Single Crystal. East European Journal of Physics, (1), 240-244. https://doi.org/10.26565/2312-4334-2025-1-25