The The Green Synthesis of Copper Oxide Nanoparticles Using the Moringa Oleifera Plant and its Subsequent Characterization for Use in Energy Storage Applications
Abstract
In this study, we describe the environmentally friendly synthesis of copper oxide (CuO) and its subsequent characterization for use in supercapacitors. Using extracts from dried, finely ground Moringa Oleifera as the reducing/capping agent, we created the CuO NP. The produced NPs were then examined using X-ray Diffractometer (XRD), Ultraviolet-Visible spectroscopy, energy dispersive spectroscopy (EDS), and scanning electron microscopy (SEM). Electrochemical analysis techniques like cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) review were utilized to look at the electrochemical behavior of CuO-based electrodes. The analysis that followed determined that the green synthesize CuO NPs displayed supercapacitive behavior. This suggests that the synthesized CuO NPs will naturally encourage application as supercapacitive electrodes because it has been found that NPs absorbance varies linearly with NPs concentration, the 0.6 moles of CuO NPs produced the highest absorbance reading of 0.35 at 398 nm. The reflection spectra demonstrate that the material exhibits low reflectance properties in the medium ultraviolet region. However, as the spectra move toward the visible light region, the reflectance rises to its maximum value of 16 percent in the short ultraviolet region. The calculated crystallite sizes are as follows: 0.2 mols CuO NP, 0.3 mols CuO NP, 0.4 mols CuO NP, 0.5 mols CuO NP, and 0.6 mols CuO NP at 43.14 nm, 43.68 nm, 24.23 nm, 5.70 nm, and 12.87 nm, respectively, where Average D = 25.93 nm is the average crystalline size across all samples. the emergence of cubic grains that resemble nanorods with tube-like holes, SEM images demonstrate that CuO NPs can be distinguished from one another as seen in 0.2 mole CuO NPs.
Downloads
References
M. Heon, S. Lofland, J. Applegate, R. Nolte, E. Cortes, J.D. Hettinger, P.L. Taberna, P. Simon, P. Huang, M. Brunet, and Y. Gogotsi, “Continuous carbide-derived carbon films with high volumetric capacitance”, Energy & Environmental Science, 4(1), 135-138D (2011). https://doi.org/10.1039/c0ee00404a
D. Ahn, I. Yoo, Y.M. Koo, N. Shin, J. Kim, and T.J. Shin, “Effects of cobalt-intercalation and polyaniline coating on electrochemical performance of layered manganese oxides”, Journal of Materials Chemistry, 21(14), 5282-5289 (2011). https://doi.org/10.1039/C0JM03548C
G. Wee, W.F. Mak, N. Phonthammachai, A. Kiebele, M.V. Reddy, B.V.R. Chowdari, G. Gruner, M. Srinivasan, and S.G. Mhaisalkar, “Particle size effect of silver nanoparticles decorated single walled carbon nanotube electrode for supercapacitors”, Journal of the Electrochemical Society, 157(2), A179 (2009). https://doi.org/10.1149/1.3267874
J. Liu, J. Wang, C. Xu, H. Jiang, C. Li, L. Zhang, J. Lin, and Z.X. Shen, “Advanced energy storage devices: basic principles, analytical methods, and rational materials design”, Advanced science, 5(1), 1700322 (2018). https://doi.org/10.1002/advs.201700322
H. Zhang, and M. Zhang, “Synthesis of CuO nanocrystalline and their application as electrode materials for capacitors”, Materials Chemistry and Physics, 108(2-3), 184-187 (2008). https://doi.org/10.1016/j.matchemphys.2007.10.005
V.D. Patake, S.S. Joshi, C.D. Lokhande, and O.S. Joo, “Electrodeposited porous and amorphous copper oxide film for application in supercapacitor”, Materials Chemistry and Physics, 114(1), 6-9 (2009). https://doi.org/10.1016/j.matchemphys.2008.09.031
X. Zhang, W. Shi, J. Zhu, D.J. Kharistal, W. Zhao, B.S. Lalia, H.H. Hng, and Q. Yan, “High-power and high-energy-density flexible pseudocapacitor electrodes made from porous CuO nanobelts and single-walled carbon nanotubes”, ACS nano, 5(3), 2013-2019 (2011). https://doi.org/10.1021/nn1030719
I.M. Tiginyanu, O. Lupan, V.V. Ursaki, L. Chow, and M. Enachi, “3-11 - Nanostructures of metal oxides”, Comprehensive Semiconductor Science and Technology, 3, 396-479 (2011). https://doi.org/10.1016/B978-0-44-453153-7.00105-X
S.E. Moosavifard, M.F. El-Kady, M.S. Rahmanifar, R.B. Kaner, and M.F. Mousavi, “Designing 3D highly ordered nanoporous CuO electrodes for high-performance asymmetric supercapacitors”, ACS applied materials & interfaces, 7(8), 4851-4860 (2015). https://doi.org/10.1021/am508816t
W. Xu, S. Dai, G. Liu, Y. Xi, C. Hu, and X. Wang, “CuO nanoflowers growing on carbon fiber fabric for flexible high-performance supercapacitors”, Electrochimica Acta, 203, 1-8 (2016). https://doi.org/10.1016/j.electacta.2016.03.170
D.P. Dubal, G.S. Gund, R. Holze, H.S. Jadhav, C.D. Lokhande, and C.J. Park, “Surfactant-assisted morphological tuning of hierarchical CuO thin films for electrochemical supercapacitors”, Dalton Transactions, 42(18), 6459-6467 (2013). https://doi.org/10.1039/C3DT50275A
S.K. Shinde, D.P. Dubal, G.S. Ghodake, D.Y. Kim, and V.J. Fulari, “Nanoflower-like CuO/Cu (OH) 2 hybrid thin films: Synthesis and electrochemical supercapacitive properties”, Journal of Electroanalytical Chemistry, 732, 80-85 (2014). https://doi.org/10.1016/j.jelechem.2014.09.004
G. Fan, and F. Li, “Effect of sodium borohydride on growth process of controlled flower-like nanostructured Cu2O/CuO films and their hydrophobic property”, Chemical engineering journal, 167(1), 388-396 (2011). https://doi.org/10.1016/j.cej.2010.12.090
H. Li, S. Yu, and X. Han, “Fabrication of CuO hierarchical flower-like structures with biomimetic superamphiphobic, self-cleaning and corrosion resistance properties”, Chemical Engineering Journal, 283, 1443-1454 (2016). https://doi.org/10.1016/j.cej.2015.08.112
Y. Ma, H. Li, R. Wang, H. Wang, W. Lv, and S. Ji, “Ultrathin willow-like CuO nanoflakes as an efficient catalyst for electro-oxidation of hydrazine”, Journal of Power Sources, 289, 22-25 (2015). https://doi.org/10.1016/j.jpowsour.2015.04.151
Y. Ma, H. Wang, J. Key, S. Ji, W. Lv, and R. Wang, “Control of CuO nanocrystal morphology from ultrathin “willow-leaf” to “flower-shaped” for increased hydrazine oxidation activity”, Journal of Power Sources, 300, 344-350 (2015). https://doi.org/10.1016/j.jpowsour.2015.09.087
D.P. Dubal, G.S. Gund, R. Holze, and C.D. Lokhande, “Mild chemical strategy to grow micro-roses and micro-woolen like arranged CuO nanosheets for high performance supercapacitors”, Journal of Power Sources, 242, 687-698 (2013). https://doi.org/10.1016/j.jpowsour.2013.05.013
G. Wang, J. Huang, S. Chen, Y. Gao, and D. Cao, “Preparation and supercapacitance of CuO nanosheet arrays grown on nickel foam”, Journal of Power Sources, 196(13), 5756-5760 (2011). https://doi.org/10.1016/j.jpowsour.2011.02.049
A.C. Nwanya, D. Obi, K.I. Ozoemena, R.U. Osuji, C. Awada, A. Ruediger, M. Maaza, F. Rosei, and F.I. Ezema, “Facile synthesis of nanosheet-like CuO film and its potential application as a high-performance pseudocapacitor electrode”, Electrochimica Acta, 198, 220-230 (2016). https://doi.org/10.1016/j.electacta.2016.03.064
W. Zhang, H. Wang, Y. Zhang, Z. Yang, Q. Wang, J. Xia, and X. Yang, “Facile microemulsion synthesis of porous CuO nanosphere film and its application in lithium-ion batteries”, Electrochimica Acta, 113, 63-68 (2013). https://doi.org/10.1016/j.electacta.2013.09.043
J. Wang, and W.D. Zhang, “Fabrication of CuO nanoplatelets for highly sensitive enzyme-free determination of glucose”, Electrochimica Acta, 56(22), 7510-7516 (2011). https://doi.org/10.1016/j.electacta.2011.06.102
F. Cao, X.H. Xia, G.X. Pan, J. Chen, and Y.J. Zhang, “Construction of carbon nanoflakes shell on CuO nanowires core as enhanced core/shell arrays anode of lithium ion batteries”, Electrochimica Acta, 178, 574-579 (2015). https://doi.org/10.1016/j.electacta.2015.08.055
B. Heng, C. Qing, D. Sun, B. Wang, H. Wang, and Y. Tang, “Rapid synthesis of CuO nanoribbons and nanoflowers from the same reaction system, and a comparison of their supercapacitor performance”, RSC advances, 3(36), 15719-15726 (2013). https://doi.org/10.1039/C3RA42869A
Z. Zhang, H. Che, Y. Wang, L. Song, Z. Zhong, and F. Su, “Preparation of hierarchical dandelion-like CuO microspheres with enhanced catalytic performance for dimethyldichlorosilane synthesis”, Catalysis Science & Technology, 2(9), 1953-1960 (2012). https://doi.org/10.1039/C2CY20199B
M.J. Deng, C.C. Wang, P.J. Ho, C.M. Lin, J.M. Chen, and K.T. Lu, “Facile electrochemical synthesis of 3D nano-architectured CuO electrodes for high-performance supercapacitors”, Journal of Materials Chemistry A, 2(32), 12857-12865 (2014). https://doi.org/10.1039/C4TA02444C
A. Vlad, N. Singh, J. Rolland, S. Melinte, P.M. Ajayan, and J.F. Gohy, “Hybrid supercapacitor-battery materials for fast electrochemical charge storage”, Scientific reports, 4, 4315 (2014). https://doi.org/10.1038/srep04315
G. Wang, L. Zhang, and J. Zhang, “A review of electrode materials for electrochemical supercapacitors”, Chemical Society Reviews, 41(2), 797-828 (2012). https://doi.org/10.1039/C1CS15060J
X. Zhang, W. Shi, J. Zhu, D.J. Kharistal, W. Zhao, B.S. Lalia, H.H. Hng, and Q. Yan, “High-power and high-energy-density flexible pseudocapacitor electrodes made from porous CuO nanobelts and single-walled carbon nanotubes”, ACS nano, 5(3), 2013-2019 (2011). https://doi.org/10.1021/nn1030719
T.M. Abdelghany, A.M. Al-Rajhi, M.A. Al Abboud, M.M. Alawlaqi, A. GanashMagdah, E.A. Helmy, and A.S. Mabrouk, “Recent advances in green synthesis of silver nanoparticles and their applications: about future directions. A review”, BioNanoScience, 8(1), 5-16 (2018). https://doi.org/10.1007/S12668-017-0413-3
M. Nasrollahzadeh, F. Ghorbannezhad, Z. Issaabadi, and S.M. Sajadi, “Recent developments in the biosynthesis of Cu‐based recyclable nanocatalysts using plant extracts and their application in the chemical reactions”, The Chemical Record, 19(2-3), 601 643 (2019). https://doi.org/10.1002/tcr.201800069
M. Nasrollahzadeh, S. Mahmoudi‐GomYek, N. Motahharifar, and M.G. Gorab, “Recent developments in the plant‐mediated green synthesis of Ag‐based nanoparticles for environmental and catalytic applications”, The Chemical Record, 19(12), 2436 2479 (2019). https://doi.org/10.1002/tcr.201800202
M. Nasrollahzadeh, M. Atarod, M. Sajjadi, S.M. Sajadi, and Z. Issaabadi, “Plant-mediated green synthesis of nanostructures: mechanisms, characterization, and applications”, in: Interface science and technology, Vol. 28, (Elsevier, Amsterdam, 2019). pp. 199-322.
M. Shah, D. Fawcett, and S. Sharma, S.K. Tripathy and G.E.J. Poinern, “Green Synthesis of Metallic Nanoparticles via Biological Entities”, Materials (Basel), 8(11), 7278–7308 (2015). https://doi.org/10.3390%2Fma8115377
V.V. Gusel'nikova, and D. Korzhevskiy, “NeuN as a neuronal nuclear antigen and neuron differentiation marker”, Acta Naturae, 7(2), 42-47 (2015). https://pubmed.ncbi.nlm.nih.gov/26085943
C.P. Devatha, and A.K. Thalla, “Green synthesis of nanomaterials”, Synthesis of inorganic nanomaterials, 169-184 (2018). https://doi.org/10.1016/B978-0-08-101975-7.00007-5
H. Duan, D. Wang, and Y. Li, “Green chemistry for nanoparticle synthesis”, Chemical Society Reviews, 44(16), 5778-5792 (2015). https://doi.org/10.1039/C4CS00363B
L. Gopalakrishnan, K. Doriya, and D.S. Kumar, “Moringa oleifera: A review on nutritive importance and its medicinal application”, Food science and human wellness, 5(2), 49-56 (2016). https://doi.org/10.1016/j.fshw.2016.04.001
R.K. Saini, I. Sivanesan, and Y.S. Keum, “Phytochemicals of Moringa oleifera: a review of their nutritional, therapeutic and industrial significance”, Biotech, 6(2), 1-14 (2016). https://doi.org/10.1007/s13205-016-0526-3
P. Scherrer, “Bestimmungdergrosse und der innerenstruktur yon kolloiteilchenmittels”, Gott. Nachr Math. Phys, 2, 98-100 (1918).
S.K. Shindea, M.B. Jalak, G.S. Ghodake, N.C. Maile, V.S. Kumbhar, D.S. Lee, V.J. Fulari, and D.-Y. Kim, “Chemically synthesized nanoflakes-like NiCo2S4 electrodes for high-performance supercapacitor application”, Appl. Surf. Sci. 466, 822 829 (2019). https://doi.org/10.1016/j.apsusc.2018.10.100
H.E. Nsude, K.U. Nsude, G.M. Whyte, R.M. Obodo, C. Iroegbu, M. Maaza, and F.I. Ezema, “Green synthesis of CuFeS2 nanoparticles using mimosa leaves extract for photocatalysis and supercapacitor applications”, Journal of Nanoparticle Research, 22(11), 1-13 (2020). https://doi.org/10.1007/s11051-020-05071-7
S. Najib, F. Bakan, N. Abdullayeva, R. Bahariqushchi, S. Kasap, G. Franzò, et al, “Tailoring morphology to control defect structures in ZnO electrodes for high-performance supercapacitor devices”, Nanoscale, 12(30), 16162-16172 (2020). https://doi.org/10.1039/D0NR03921G
M.Ö. Alaş, A. Güngör, R. Genç, and E. Erdem, “Feeling the power: robust supercapacitors from nanostructured conductive polymers fostered with Mn 2+ and carbon dots”, Nanoscale, 11(27), 12804-12816 (2019). https://doi.org/10.1039/C9NR03544C
M. Toufani, S. Kasap, A. Tufani, F. Bakan, S. Weber, and E. Erdem, “Synergy of nano-ZnO and 3D-graphene foam electrodes for asymmetric supercapacitor devices”, Nanoscale, 12(24), 12790-12800 (2020). https://doi.org/10.1039/D0NR02028A
A.O. Aliyu, S. Garba, and O. Bognet, “Green Synthesis, Characterization and Antimicrobial Activity of Vanadium Nanoparticles Using Leaf Extract of Moringa Oleifera,” 11(1), 42–48 (2018). https://doi.org/10.9790/5736-1101014248
A.A. Radhakrishnan, and B.B. Beena, “Structural and Optical Absorption Analysis of CuO Nanoparticles”, Indian Journal of Advances in Chemical Science, 2(2), 158–161 (2014). https://www.ijacskros.com/artcles/IJACS-M64.pdf
D. Deng, T. Qi, Y. Chen, Y. Jin, and F. Xiao, “Preparation of antioxidative nano copper pastes for printed electronics application,” in: 13th International Conference on Electronic Packaging Technology & High Density Packaging, (2012). pp. 250-253. https://doi.org/10.1109/ICEPT-HDP.2012.6474611
S.F. Shaffiey, M. Shapoori, A. Bozorgnia, and M. Ahmadi, “Synthesis and evaluation of bactericidal properties of CuO nanoparticles against Aeromonas hydrophila”, Nanomedicine Journal, 1(3), 198–204 (2014). https://doi.org/10.7508/nmj.2014.03.010
Copyright (c) 2023 Imosobomeh L. Ikhioya, Edwin U. Onoh, Agnes C. Nkele, Bonaventure C. Abor, B.C.N. Obitte, M. Maaza, Fabian I. Ezema
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).
