Mutual solubility in nanosized Au-Ni system

  • С. И. Богатыренко Харьковский национальный университет имени В. Н. Каразина
Keywords: thin films, Au-Ni, mutual solubility.

Abstract

The results of experimental studies of the effect of size on the solid state mutual solubility in a binary Au (35 at. %)-Ni film system have been reported. Film systems were formed by successive condensation of the components from independent sources in a high vacuum. The formation of a solid solution was detected by ED while heating directly in the PEM-125K electron microscope. It has been found that the formation of a uniform solid solution in layered Au-Ni film system with total thickness of 23 nm takes place at425 °C. This value is substantially lower than appropriate for macroscopic systems one.

 

 

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Author Biography

С. И. Богатыренко, Харьковский национальный университет имени В. Н. Каразина
С.н.с.

References

Junggoo Lee, Joonho Lee, Toshihiro Tanaka, at al. Phase Diagrams of Nanometer-Sized Particles in Binary Systems // Research Center for Ultra-High Voltage Electron Microscopy. — Osaka University. — 2005. — P. 56–59.

Liang L. H., Liu D. and Jiang Q. Size-depen dent continuous binary solution phase dia gram. // Institute of Physics Publishing Nano technology. Nanotechnology 14. — 2003. — P. 438–442. PII: S0957–4484(03)55857–3.


Поверхностные явления и фазовые превра щения в конденсированных пленках / Под ред. Н. Т. Гладких. — Харьков.: ХНУ им. В. Н. Каразина, 2004. — 276 с.


Иевлев В. М., Трусов Л. И., Холмянский В. А. // Структурные превращения в тон ких пленках. — Москва.: «Металлургия», 1982.


Палатник Л. С., Бойко Б. Т. О диаграмме состояния сплавов Al-Cu в тонких пленках // ФММ. — 1961. — Т. 11, № 1. — С. 123–127.


Joonho Lee a, Joongchul Park a, Toshihiro Tanaka. Effects of interaction parameters and melting points of pure metals on the phase diagrams of the binary alloy nanoparticle systems: A classical approach based on the regular solution model // CALPHAD: Computer Coupling of
Phase Diagrams and Thermo chemistry. — 2009. — Vol. 33.— P. 377–381.


Eli A. Sutter, Peter W. Sutter. Giant carbon solubility in Au nanopartcles // J Mater Sci. — 2011. — P. 7090–7097. — DOI 10.1007 / s10853–011–5663–9.

Jung-Goo Leea, Hirotaro Morib. TEM Stu dies on Phase Stability in Nanometer-sized Alloy Particles // Solid State Phenomena. — 2007. — Vol. 127. — P. 135–140.


Nadi Braidy, Gary R. Purdy, Gianluigi A. Botton. Equilibrium and stability of phase-se parating Au-Pt nanoparticles // Acta Materialia. — 2008. — Vol. 56, I. 20. — P. 5972–5983.

Богатыренко С. И. Формирование твердых растворов в пленочной системе Au-Ni: in situ ПЭМ исследование // ЖТФ. — 2014. — Т. 84, вып. 9. — С.113–116.

Okamoto. H. Desk Handbook. Phase Diagrams for Binary Alloys. ASM International, 2000. — 828 p.

Hobbs L. W. «Radiation Effects in Analysis of Inorganic Specimens by TEM Introduction to Analytical Electron Microscopy, 1979. — 437 p.

Smithells Colin I. Metals reference book. — Lon don.: Butterworth and Co. Publishers, 1976. — 728 c.

Гладких Н. Т., Чижик С. П., Григорьева Л. К. и др. // ДАН СССР. — 1988. — Т. 300, № 3. — С. 588–592.
Published
2017-02-24
How to Cite
Богатыренко, С. И. (2017). Mutual solubility in nanosized Au-Ni system. Journal of Surface Physics and Engineering, 13(3), 313 - 317. Retrieved from https://periodicals.karazin.ua/pse/article/view/8009