Developments of Nanoporous AAO Based Capacitive-Type Sensors for Heavy Metal Ion (Arsenic) Sensing Application

  • Trishna Moni Das Department of Applied Sciences, Gauhati University, Guwahati, Assam, India https://orcid.org/0000-0001-5754-5608
  • Devabrata Sarmah Centre of Excellence in Nanotechnology, Assam down town University, Guwahati, Assam, India
  • Sankar Moni Borah Department of Applied Sciences, Gauhati University, Guwahati, Assam, India
  • Sunandan Baruah bCentre of Excellence in Nanotechnology, Assam down town University, Guwahati, Assam, India https://orcid.org/0000-0003-2963-6128
Keywords: Capacitive-type sensor, Nanoporous Anodic Aluminum Oxide (AAO), Anodization, Energy dispersive X-ray spectroscopy (EDS)

Abstract

In this work the evolution of a capacitive type sensor based on nanoporous anodic aluminum oxide (AAO) fabricated by a two-step anodization process using a low-cost customized setup designed in-house is reported. The parallel plate capacitors were fabricated using aluminum (Al) as base electrode and gold as top electrode, where the porous AAO was used as the dielectric material. This demonstrated the clear dependence of the capacitance values of the as prepared different sensors on the dielectric material’s thickness. The as developed sensors were tested for the detection of arsenic (As) ions.An increase in the capacitance was observed while increasing the concentration of the As ion in aqueous solutions. The presence of As ion was confirmed through EDS (Energy dispersive X-ray spectroscopy) mapping carried out in a FESEM. This change in capacitance can be attributed to the change in dielectric constant of the active material with the incorporation of metal ions.

Downloads

Download data is not yet available.

References

M.A. Kashi, and A. Ramazani, “The effect of Temperature and Concentration on the Self-Organized Pore Formation in Anodic Alumina,” J. Phys. D: Appl. Phys. 38, 2396 (2005).https://doi.org/10.1088/0022-3727/38/14/015

H. Masuda, F. Matsumoto, and, K. Nishio, “Fabrication of Functional Devices Based on Highly Ordered Anodic Porous Alumina,” Electrochemistry, 72, 389 (2004).https://doi.org/10.5796/electrochemistry.72.389

M. Iwai, T. Kikuchi, andR.O. Suzuki, “Self-Ordered Nanospike Porous Alumina Fabricated under a New Regime by an Anodizing Process in Alkaline Media,” Sci. Rep.11, 7240 (2021).https://doi.org/10.1038/s41598-021-86696-z

T. Islam, A.T. Nimal, U. Mittal,and M.U. Sharma, “A Micro Interdigitated Thin Film Metal Oxide Capacitive Sensor for Measuring Moisture in the Range of 175-625 Ppm,” Sens. Actuators B Chem. 221, 357 (2015).https://doi.org/10.1016/j.snb.2015.06.101

J.O. Carneiro, A. Ribeiro, F. Miranda, I.R. Segundo, S. Landi, V. Teixeira, and M.F.M. Costa, “Development of Capacitive-Type Sensors by Electrochemical Anodization: Humidity and Touch Sensing Applications,” Sensors,21, 7317 (2021).https://doi.org/10.3390/s21217317

M.A. Kashi, A. Ramazani, H. Abbasian,and A. Khayyatian, “Capacitive Humidity Sensors Based on Large Diameter Porous Alumina Prepared by High Current Anodization,” Sens. Actuators A, Phys. 174, 69 (2012).https://doi.org/10.1016/j.sna.2011.11.033

C.K. Chung, C.A. Ku, andZ.E. Wu, “A High-and- Rapid- Response Capacitive Humidity Sensor of Nanoporous Anodic Alumina by One- step Anodizing Commercial 1050 Aluminum Alloy and Its Enhancement Mechanism,” Sens. Actuators B, Chem. 343, 130156 (2021).https://doi.org/10.1016/j.snb.2021.130156

M.A. Mir, M.A. Shah, and P.A. Ganai, “Nanoporous Anodic Alumina (NAA) Prepared in Different Electrolytes with Different Pore Sizes for Humidity Sensing,” J. Solid State Electrochem. 24, 1679 (2020).https://doi.org/10.1007/s10008-020-04683-2

S.W. Chen, O.K. Khor, M.W. Liao, andC.K. Chung, “Sensitivity Evolution and Enhancement Mechanism of Porous Anodic Aluminum Oxide Humidity Sensor Using Magnetic Field,” Sens. Actuators B, Chem. 199, 384 (2014).https://doi.org/10.1016/j.snb.2014.03.057

C.K. Chung, O.K. Khor, C.J. Syu, andS.W. Chen, “Effect of Oxalic acid Concentration on the Magnetically Enhanced Capacitance and Resistance of AAO Humidity Sensor,” Sens. Actuators B, Chem. 210, 69 (2015).https://doi.org/10.1016/j.snb.2014.12.096

J. Wu, M. Cao, D. Tong, Z. Finkelstein, andE.M.V. Hoek, “Acritical review of point-of-use drinking water treatment in the United States,” Npj Clean Water.4, 40 (2021).https://doi.org/10.1038/s41545-021-00128-z

L. Weerasundara, Y.-S. Ok, andJ. Bundschuh, “Selective removal of arsenic in water: A critical review,” Environ. Pollut. 268, 115668 (2021).https://doi.org/10.1016/j.envpol.2020.115668

Md. G. Uddin, S. Nash, andA.I. Olbert, “A review of water quality index models and their use for assessing surface water quality,” Ecol.Indicat. 122, 107218 (2021).https://doi.org/10.1016/j.ecolind.2020.107218

L. Zheng, Z. Zhou, M. Rao, and Z. Sun, “Assessment of heavy metals and arsenic pollution in surface sediments from rivers around a uranium mining area in East China,” Environ Geochem Health,42, 1401 (2020).https://doi.org/10.1007/s10653-019-00428-x

H. Ahmad, A.R.A. Abdulwahab, B.H. Koo, and R.A. Khan, “Selective Extraction of Trace Arsenite Ions Using a Highly Porous Aluminum Oxide Membrane with Ordered Nanopores,” ACS Omega,7, 3044 (2022).https://doi.org/10.1021/acsomega.1c06133

A.P. Li, F. Müller, A. Birner, K. Nielsch, andU. Gösele, “Hexagonal Pore Arrays with a 50-420 nm Interpore Distance Formed by Self-Organization in Anodic Alumina,” J. Appl. Phys.84, 6023 (1998).https://doi.org/10.1063/1.368911

Published
2024-03-05
Cited
How to Cite
Das, T. M., Sarmah, D., Borah, S. M., & Baruah, S. (2024). Developments of Nanoporous AAO Based Capacitive-Type Sensors for Heavy Metal Ion (Arsenic) Sensing Application. East European Journal of Physics, (1), 426-431. https://doi.org/10.26565/2312-4334-2024-1-45