Investigation of the Structural Composition of Fe-Mn-Si-Ti-Al-N-C Alloys and the Solubility of Elements in α-Iron

  • Nataliia Filonenko Dnipro State Medical University, Dnipro, Ukraine; Z. I. Nekrasov Iron and Steel Institute of National Academy of Sciences of Ukraine, Dnipro, Ukraine https://orcid.org/0000-0003-1219-348X
  • Olexander Babachenko Z. I. Nekrasov Iron and Steel Institute of National Academy of Sciences of Ukraine, Dnipro, Ukraine https://orcid.org/0000-0003-4710-0343
  • Hanna Kononenko Z. I. Nekrasov Iron and Steel Institute of National Academy of Sciences of Ukraine, Dnipro, Ukraine https://orcid.org/0000-0001-7446-4105
  • Alexander Baskevich Ukrainian State University of Chemical Technology, Dnipro, Ukraine https://orcid.org/0000-0002-3227-5637
Keywords: complex alloying of steel with aluminum, titanium and nitrogen, inclusions, oxides, nitrides, carbonitrides, ferrite, free energy of ferrite

Abstract

The study of the structural components of Fe-Mn-Si-Ti-Al-N-C with the carbon content of 0.50-0.60% (wt.), Silicon 0.80-0.90% (wt.), Manganese 0.90-0.95% ( wt. ), Aluminum - 0.20-0.30% (wt.), Titanium - 0.02-0.03% (wt.), Nitrogen - 0.015-0.02% (wt.), the rest - iron. Microstructural, micro-X-ray spectral and X-ray phase analyzes were used to determine the structural state of the alloys. It is shown that after crystallization and a number of phase transformations the structure of the alloy was presenteda - iron alloyed with cementite, oxides, nitrides and carbonitrides. Using the quasi-chemical method, the free energy dependence of the solid solution of α-iron alloyed with silicon, manganese and titanium was obtained. In α-iron, it can dissolve up to 0.016% (at.) Carbon, manganese up to 1.3% (at.), Silicon - 1.0% (at.), and titanium up to 0.5% (at.), which is consistent with experimental results.

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References

Y. Tu, L. Huang,, et al., Materials Science and Technology, 34(7), 780 (2018), https://doi.org/10.1080/02670836.2017.1407558

C. Zhu, et. al. Ultramicroscopy, 107(9), 808 (2007), https://doi.org/10.1016/j.ultramic.2007.02.033

G. Miyamoto, Oh J, Hono K, et al., Acta Mater. 55(15), 5027 (2007), https://doi.org/10.1016/j.actamat.2007.05.023

Y.Y. Tu, Z. G. Mao, Q. Zhang, et. al, Mater Lett. 134, 84 (2014), https://doi.org/10.1016/j.matlet.2014.07.057

І. Gutierrez-Urrutia, ISIJ International, 61(1), 16 (2021), https://doi.org/10.2355/isijinternational.ISIJINT-2020-467

N. Filonenkoa A. Babachenko, G. Kononenko, and E. Domin, East. Eur. J. Phys, 4, 90 (2020), https://doi.org/10.26565/2312-4334-2020-4-12

J. Miettinen, V.-V. Visuri, and T. Fabritius, Thermodynamic description of the Fe–Al–Mn–Si–C system for modelling solidification of steels, (University of Oulu, Oulu, 2019). pp. 704, http://jultika.oulu.fi/files/isbn9789526222516.pdf

P. Głowacz, M. Tenerowicz-Żaba, M. Sułowski, and J. Konstanty, International Journal NDTDays, II(3), (2019).

Ch. Krishna Ande, H.F. Marce, Metallurgical and Materials Transactions, A 4436, 43A (2012), https://doi.org/10.1007/s11661-012-1229-y

S.V. Tverdokhlebova, Vіsnyk Dnіpropetrovskogo nacіonalnogo unіversitetu. Serіja Fіzika. Radіoelektronіka, 14(12/1), 100 (2007).

O.V. Akymov, and S.M. Nury, Eastern-European Journal of Enterprise Technologies, 6(11/78), 35 (2015), https://doi.org/10.15587/1729-4061.2015.56370

A.P. Huliaev, and A.A. Huliaev, Металловедение [Metalscience], (Midalliance, 2011), pp. 644. (in Russian)

M.P. Shaskolskaya, Кристаллография [Crystallography], (Vyisshay Shkola, Moscow, 1984), pp.376. (in Russian)

Z.A. Matysina, and M.I. Milyan, Теория растворимости примеси в упорядоченных фазах [Solubility theory residual element in ordered phase], (DGU, Dnipro, 1991). pp.180.(in Russian).

Citations

Effect of microalloying of carbon steel with titanium, aluminum and nitrogen on structural peculiarities and mechanical properties
Filonenko N. Yu., Babachenko О. І. & Kononenko G. A. (2023) Fundamental and applied problems of ferrous metallurgy
Crossref

Magnetic Properties of Silicon with Paramagnetic Impurity Atoms
Zikrillayev Nurulla F., Mavlonov Giyosiddin Kh., Trabzon Levent, Koveshnikov Sergey V., Kenzhaev Zoir T., Ismailov Timur B. & Abduganiev Yoldoshali A. (2023) East European Journal of Physics
Crossref

Published
2021-12-10
Cited
How to Cite
Filonenko, N., Babachenko, O., Kononenko, H., & Baskevich, A. (2021). Investigation of the Structural Composition of Fe-Mn-Si-Ti-Al-N-C Alloys and the Solubility of Elements in α-Iron. East European Journal of Physics, (4), 120-123. https://doi.org/10.26565/2312-4334-2021-4-14