The Child-Langmuir Collisional Laws for the Cathode Sheath of Glow Discharge in Nitrogen

  • Valeriy Lisovskiy V.N. Karazin Kharkiv National University https://orcid.org/0000-0002-6339-4516
  • V. Derevyanko V.N. Karazin Kharkiv National University
  • Vladimir Yegorenkov V.N. Karaziv Kharkov National University
Keywords: glow discharge, cathode sheath, positive ions, nitrogen, the Child-Langmuir law

Abstract

This communication reports the measurements of dc sheath thickness d together with the voltage drop U across it at different current I values in nitrogen. For the case of a narrow gap when the discharge consists only of a cathode sheath and a negative glow almost all voltage applied across the electrodes drops across the cathode sheath. We observe that at the nitrogen pressure p < 1 Torr, as well as for p > 1.5 Torr the Child-Langmuir collisional law version characterized by the constant ion mobility is valid. Within the pressure range of 1 < p < 1.5 Torr none of Child-Langmuir law versions (with a constant mobility or a constant ion mean free path) are not applicable for the description of the dc cathode sheath in nitrogen. The available references enable us to conclude that at p < 1 Torr the discharge is dominated by N+ ions whereas for p > 1.5 Torr N4+ ions dominate. These ions are not prone to charge exchange with N2 molecules and they move in the dc cathode sheath with constant mobility. Within the pressure range of 1 < p < 1.5 Torr the discharge contains N+, N2+, N3+ and N4+ ions in comparable concentrations therefore none of the Child-Langmuir law versions can be valid.

Downloads

Download data is not yet available.

References

Schmidt B., Wetzig K. Ion Beams in Materials Processing and Analysis. – Wien: Springer, 2013. – 418 p.

Harry J. Introduction to Plasma Technology: Science, Engineering and Applications. – Weinheim: Wiley, 2010. – 215p.

Fridman A. Plasma Chemistry. – Cambridge: Cambridge University Press, 2008. – 978 p.

Lieberman M.A., Lichtenberg A.J. Principles of plasma discharges and materials processing. - New York: Wiley, 2005. – 757p.

Raizer Y.P. Gas Discharge Physics. - Berlin: Springer, 1991. - 450p.

Child C.D. Discharge From Hot CaO // Phys. Rev. – 1911. – Vol. 32, №5. – P. 492-511.

Langmuir I. The Effect of Space Charge and Residual Gases on Thermionic Currents in High Vacuum // Phys. Rev. – 1913. – Vol.2, №6. – P. 450–486.

Langmuir I. The Effect of Space Charge and Initial Velocities on the Potential Distribution and Thermionic Current between Parallel Plane Electrodes // Phys. Rev. - 1923. – Vol.21, №4. – P. 419–435.

Langmuir I. The Interaction of Electron and Positive Ion Space Charges in Cathode Sheaths // Phys. Rev. - 1929. – Vol.33, №6. - P. 954–989.

McDaniel E.W., Mason E.A. The Mobility and Diffusion of Ions in Gases. - New York: Wiley, 1973. – 424p.

Lisovskiy V., Yegorenkov V. Validating the collision-dominated Child–Langmuir law for a dc discharge cathode sheath in an undergraduate laboratory // Eur. J. Phys. – 2009. – Vol. 30, № 6. – P. 13451351.

Lisovskiy V.A., Yakovin S.D. Experimental Study of a Low-Pressure Glow Discharge in Air in Large-Diameter Discharge Tubes: I. Conditions for the Normal Regime of a Glow Discharge // Plasma Physics Reports. – 2000. – Vol.26, №12. – P.1066 1075.

Lisovskiy V.A., Kharchenko N.D., Fateev R.N. Normal mode of the dc discharge in low pressure nitrogen // The Journal of Kharkiv National University, Physical series: Nuclei, Particles, Fields. - 2009. - №4. - P.75-83.

Lisovskiy V.A., Artushenko E.P., Derevyanko V.A., Yegorenkov V.D. Normal and abnormal regimes of dc discharge burning in N2O // Problems of Atomic Science and Technology. - 2013. - №1. - P.210-212.

Mitchell J.H., Ridler K.E.W. The speed of positive ions in nitrogen // Proc. of the Royal Society A. - 1934. - Vol.146, №10. - P. 911-921.

Varney R.N. Drift velocity of ions in oxygen, nitrogen, and carbon monoxide // Phys. Rev. - 1953. - Vol.89, №4. - P.708-711.

Kovar F.R., Beaty E.C., Varney R.N. Drift velocities of ions in nitrogen at various temperatures // Phys. Rev. - 1957. - Vol.107, №6. - P.1490-1492.

Dalgarno A. The mobilities of ions in their parent gases // Philos. Trans. Of the Royal Society A. - 1958. - Vol.250, №4. - P.426-439.

Saporoschenko M. Ions in nitrogen // Phys. Rev. - 1958. - Vol.111, №6. - P.1550-1553.

Varney R.N. Molecular ions // J. Chem. Phys. - 1959. - Vol. 31, № 5. - P.1314-1316.

Dahlquist J.A. Drift velocities of ions in nitrogen // J. Chem. Phys. - 1963. - Vol. 39, № 5. - P.1203-1206.

Woo Sh.-B. Conversion of ion types in nitrogen // J. Chem. Phys. - 1965. - Vol. 42, № 4. - P.1251-1261.

Saporoschenko M. Mobility of mass-analyzed N+, N2+, N3+, and N4+ ions in nitrogen gas // Phys. Rev. - 1965. - Vol.139, №2A. - P.352-356.

Samson J.A.R., Weissler G.L. Mobilities of oxygen and nitrogen ions // Phys. Rev. - 1965. - Vol.137, №2A. - P.381-383.

Shanin M.M. Ion-molecule interaction in the cathode region of a glow discharge // J. Chem. Phys. - 1965. - Vol. 43, № 5. - P.1798-1805.

Keller G.E., Martin D.W., McDaniel E.W. General considerations comcerning apparent mobilities in mixed ion populations: Drift velocities of mass-identified N+, N2+, N3+, and N4+ ions in nitrogen // Phys. Rev. - 1965. - Vol.140, №5A. - P.1535-1546.

Bloomfield C.H., Hasted J.B. Interconversion of ions drifting in a gas // Brit. J. Appl. Phys. - 1966. - Vol.17, №4. - P.449-460.

McKnight L.G., McAfee K.B., Sipler D.P. Low-field drift velocities and reactions of nitrogen ions in nitrogen // Phys. Rev. - 1967. - Vol.164, №1. - P.62-70.

Moseley J.T., Snuggs R.M., Martin D.W., McDaniel E.W. Mobilities, diffusion coefficients, and reaction rates of mass-identified nitrogen ions in nitrogen // Phys. Rev. - 1969. - Vol.178, №1. - P.240-248.

Huntress W.T. Ion cyclotron resonance power absorption: Collision frequencies for CO2+, N2+, and H3+ ions in their parent gases // J. Chem. Phys. - 1971. - Vol. 55, № 5. - P.2146-2155.

Guerra V., Galiaskarov E., Loureiro J. Dissociation mechanisms in nitrogen discharges // Chem. Phys. Lett. - 2003. - Vol.371, №5-6. - P.576-581.

Guerra V., Sa P.A., Loureiro J. Role played by the N2(A 3Su+) metastable in stationary N2 and N2-O2 discharges // J. Phys. D: Appl. Phys. - 2001. - Vol.34, №12. - P.1745-1755.

Guerra V., Sa P.A., Loureiro J. Electron and metastable kinetics in the nitrogen afterglow // Plasma Sources Sci. Technol. - 2003. - Vol.12, №4. - P.S8-S15.

Engel A.Von. Ionized Gases. – Oxford: Clarendon Press, 1955.

Published
2013-06-01
Cited
How to Cite
Lisovskiy, V., Derevyanko, V., & Yegorenkov, V. (2013). The Child-Langmuir Collisional Laws for the Cathode Sheath of Glow Discharge in Nitrogen. East European Journal of Physics, (1059(3), 75-82. Retrieved from https://periodicals.karazin.ua/eejp/article/view/13033