Spectrophotometric determination of zineb with disulfophenylfluorone and polyhexamethyleneguanidine chloride

doi:10.26565/2220-637X-2012-21-26

T. S. Chmilenko O. Honchar Dnipropetrovsk National University
L. A. Ivanica O. Honchar Dnipropetrovsk National University
F. A. Chmilenko O. Honchar Dnipropetrovsk National University

DOI: https://doi.org/10.26565/2220-637X-2012-21-26

Keywords: spectrophotometry, zinc ethylene-bis-dithiocarbamate, 2,4-difulfophenylfluorone, polyhexamethyleneguanidine chloride, ternary metal-polymer complex

Abstract

Spectrophotometric method for the determination of Zineb in potatoes and commercial sample of fungicide in the form of ternary metal-polymer complex disulfophenylfluorone–polyhexamethyleneguanidine chloride – Zn is presented. Optimal conditions, spectrophotometric characteristics of the complex and the effect of foreign ions and derivatives of dithiocarbamates is determined. The procedure with the using of TMPC allows to determine the content of Zineb in the concentration range of 0,1-10,0 mg/l.

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References

Ivanova S.N. Fungicidy' i ih primenenie // Trudy' Vsesoyuznogo himicheskogo obsch'estva im. D.N. Mendeleeva. -1964. - T. 9. – №5. - PP. 496-503.

Malik A.K., Kapoor J., Rao A.L.J. Simple and sensitive spectrophotometric determination of ziram, zineb and ferbam in commercial samples and foodstuffs using phenyluorone / J. Envi-ron. Monit. – 2000. – №2. – РP. 367-371.

Zaijun L, You F, Zhongyun L, Jian T. Spectrophotometric determination of iron(III)-dimethyldithiocarbamate (ferbam) using 9-(4-carboxyphenyl)-2,3,7-trihydroxyl-6-fluorone / Talanta, 2004. – V. 63. – Р. 647-651.

Pat. RU № 2013771. Sposob kolichestvennogo opredeleniya cineba v kormovy'h korneplodah // Haliulin G.L., Studencov Yu.V., Marushkin E.A., Smetov P.K. Opubl. 30.05.1994.

Prez-Ruiz T., Martinez-Lozano C., Toms V., Casajs R. Flow-injection fluorimetric determina-tion of nabam and metham / Talanta. – 1996. – V. 43. – РP. 193-201.

Peregud E. A. Sanitarno-himicheskiy kontrol' vozdushnoy sredy'. Spravochnik. L.: Himiya, 1978. - 336 p.

Chmilenko T. S. Analiticheskaya himiya polie`lektrolitov i ih primenenie v analize : monogr. / T. S. Chmilenko, F. A. Chmilenko. - D.: DNU, 2012. - 224 p.

Mel'nikov N.N. Pesticidy'. - M.: Himiya, 1987. — 712 p.

Korostelev P.P. Prigotovlenie rastvorov dlya himiko-analiticheskih rabot. Izd. 2-e, pererab. i dop. - M.: Nauka, 1964. - 202 p.

Nijnik V.V., Nijnik T.YU., Malisheva M.L., Astreli'n I'.M. Asoci'aci'ya i'oni'v metali'v z vodorozchinnim poli'geksametilenguani'dinom solyanokislim / Vopr. himii i himtehn. - 2006. - №6. - PP. 120-124.

Chmilenko T.S., Klyuchnik L.O., Pshedzyal A.M., Chmilenko F.O. Asoci'ati di-sul'fofeni'lfluoronu z poli'geksametilenguani'dinom yak anali'tichna forma dlya viznachennya vi'tami'nu B12 // Vopr. himii i himtehn. - 2011. - №5. - PP. 85-89.

Chmilenko T.S., Che'rny'y A.N., Chmilenko F.A. Spektrofotometrncheskoe opredelenie ko-bal'ta(P) s 4-(2-piridnlazo)rezorcnnom v prisutstvii poligeksametilenguanidiniy hlorida // Vestn. DNU: Ximiya. - 2010. - №12. - PP. 10-14.

Chmilenko T.S., Che'rny'y A.N., Solov'e'va A.S., Chmilenko F.A. Opredelenie soderjaniya metallov sistemoy azokrasitel'-poligeksametilenguanidiniy hlorid-sol' metalla / Bestn. DNU. Ser. Paketno-kosmicheskaya tehnika.-2010.- №15. - PP. 47-53.

Nazarenko V.A., Biryuk E.A., Rubel' A.P., Ul'yanova T.N. Trioksifluorony' kak fotomet-richeskie reagenty' na cink / J. Analit. Chem. - 1978. - T. 33. - №5. - PP. 903-908.

Chmilenko T.S., Klyuchnik L.A., Bohan Yu.V., Chmilenko F.A. Osobennosti povedeniya salicilfluorona v vodno-polie`lektrolitny'h rastvorah / Vopr. himii i himtehn. - 2010. - №6. - PP. 86-91.