Efficiency of energy transport in luminescent molecular nanoclusters (j-aggregates)

Authors

  • R. S. Grynyov Institute for Scintillation Materials, NAS of Ukraine Author
  • A. V. Sorokin Institute for Scintillation Materials, NAS of Ukraine Author
  • G. Ya. Guralchuk Institute for Scintillation Materials, NAS of Ukraine Author
  • S. L. Yefimova Institute for Scintillation Materials, NAS of Ukraine Author
  • I. A. Borovoy Institute for Scintillation Materials, NAS of Ukraine Author
  • Yu. V. Malyukin Institute for Scintillation Materials, NAS of Ukraine Author

Keywords:

molecular nanoclusters, J-aggregates, exciton transport, exciton trap, luminescence quenching, modified Stern-Volmer equation

Abstract

Using exciton trap (polymethine dye DiD) the efficiency of exciton energy transport in luminescent molecular nanoclusters (J-aggregates) of polymethine dye amphi-PIC has been investigated. It was shown that 50% of J-aggregates luminescence is quenched at the ratio amphi-PIC/DiD = 120, which points to effective energy transfer in the J-aggregates comparing with J-aggregates of another dyes. It was revealed that embedding of surfactant CPB leads to an increase in energy transfer efficiency due to suppression of localization processes in J-aggregates. In presence of CPB 50% of J-aggregates luminescence is quenched at the ratio amphi-PIC/DiD equal to 160.

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Author Biographies

  • R. S. Grynyov, Institute for Scintillation Materials, NAS of Ukraine

    60 Lenin ave., Kharkiv 61001, Ukraine, 

    grynyov@isma.kharkov.ua

     

  • A. V. Sorokin, Institute for Scintillation Materials, NAS of Ukraine

    60 Lenin ave., Kharkiv 61001, Ukraine

     grynyov@isma.kharkov.ua

  • G. Ya. Guralchuk, Institute for Scintillation Materials, NAS of Ukraine

    60 Lenin ave., Kharkiv 61001, Ukraine

     grynyov@isma.kharkov.ua

  • S. L. Yefimova, Institute for Scintillation Materials, NAS of Ukraine

    60 Lenin ave., Kharkiv 61001, Ukraine

     grynyov@isma.kharkov.ua

  • I. A. Borovoy, Institute for Scintillation Materials, NAS of Ukraine

    60 Lenin ave., Kharkiv 61001, Ukraine

     grynyov@isma.kharkov.ua

  • Yu. V. Malyukin, Institute for Scintillation Materials, NAS of Ukraine

    60 Lenin ave., Kharkiv 61001, Ukraine

     grynyov@isma.kharkov.ua

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Published

2008-06-04

Issue

Section

Methods of biophysical investigations

How to Cite

Efficiency of energy transport in luminescent molecular nanoclusters (j-aggregates). (2008). Biophysical Bulletin, 2(21), 101-106. https://periodicals.karazin.ua/biophysvisnyk/article/view/16805

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