Luminescent properties of CsI single crystals scavenged by additions of Y3+

  • Victor L. Cherginec
  • T. P. Rebrova
  • Yu. N. Dacko
  • V. Yu. Pedash
  • R. P. Yavecky
  • S. V. Parkhomenko
Keywords: cesium iodide, acids, yttrium chloride, X-ray luminescence, the decay of scintillation pulse

Abstract

The effect of Y3+ dopant on radioluminescence spectrum form and kinetics of scintillation pulse decay in CsI single crystals grown by Bridgman-Stockbarger method is studied. The increase of Y3+ concentration does not affect the position of the basic luminescence band of CsI (lmax=307 nm at Y3+ molality of 6.7·10-4 mol∙kg-1 and lmax=306 nm at Y3+ molality of 6.7·10-3 mol∙kg-1). The maximal fraction of 7-ns component of the scintillation pulse is achieved at Y3+ molality of 6.7·10-3 моль·кг-1 and it is equal to 0.65, whereas the fraction of slow 2 ms component does not exceed 0.02.

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References

Cherginets V.L., Rebrova T.P., Datsko Yu.N., Goncharenko V.F., Kosinov N.N., Pedash V.Yu. On luminescence properties of CsI crystals scavenged by Mg2+//Mater.Lett.-2011.-V.65,N15-16.-P.2416-2418.

Cherginets V.L., Rebrova T.P., Datsko Yu.N., Pedash V.Yu., Kosinov N.N. // Visn. Hark. Nac. univ., 2011, Ser. Him., issue 20(43), P. 121-128. [ISSN 2220-637X (print), ISSN 2220-6396 (online), http://chembull.univer.kharkov.ua/archiv/2011/13.pdf] [in Russian].

Deanhardt M.L., Stern K.H. Solubility of yttrium oxide in Na2SO4 and NaCl melts// J.Electrochem.Soc.-1982.-V.129,N10.-P.2228-2232.

Cherginets V.L.,Datsko Yu.N., Rebrova T.P., Goncharenko V.F., Pedash V.Yu. // Visn.Hark. Nac. univ., 2010,Ser.Him., issue 18(41), P.203-208.[ISSN 2220-637X (print), ISSN 2220-6396 (online), http://chembull.univer.kharkov.ua/archiv/2010/26.pdf] [in Russian]

Published
2012-12-03
Cited
How to Cite
Cherginec, V. L., Rebrova, T. P., Dacko, Y. N., Pedash, V. Y., Yavecky, R. P., & Parkhomenko, S. V. (2012). Luminescent properties of CsI single crystals scavenged by additions of Y3+. Kharkiv University Bulletin. Chemical Series, (21), 308-312. https://doi.org/10.26565/2220-637X-2012-21-35