Solid-phase analytical reagents based on 1,5-diphenylcarbazone
Abstract
The possibility of use of the solid-phase analytical reagents based on 1,5- diphenylcarbazon immobilized on polyurethane foam and xerogel for the combined spectroscopic and visual-test determination of Pb(II), Cd(II), Co(II), Zn(II), Ni(II), Hg(II), Cu(II) has been studied. The conditions of modified xerogel synthesis were optimized. The material obtained is characterized by the uniform structure and high degree of retention of reagents. The solid-phase reagent can be used for the determination of the total content of heavy metals in water. The immobilization of metal complexes on polyurethane foam increases their stability compared to aqueous solutions. The metrological characteristics of the determination of studied metals were evaluated by the diffuse reflectance spectroscopy, colorimetry, and visual colorimetry. Significantly different concentration ranges of metals determined with the use of the solid-phase reagent DFK-PUF allow to recommend it for the rapid evaluation of the copper(II) content in drinking water, as well as mercury(II) after sample concentration.
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References
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