The refinement of limiting molar conductivities of weak acids and bases
Abstract
The paper emphasizes that the values of limiting molar conductivity of fairly weak acids and bases mentioned in the contemporary research papers do not comply with the action mass law; they are conventional values representing sums of limiting mobilities of the cations and anions rather than real limiting molar conductivities. Taking into account the mole fractions of different electro-lyte forms while C→0, found with strict application of the action mass law, the method of the re-finement of the values of limiting molar conductivities of weak acids and bases has been proposed.
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Damaskin B. B., Petriy O. A., Cirlina G., A. E`lektrohimiya.− M.: Himiya, KolosS, 2006. − 672 s. [in Russian]
Skorchelletti V. V.Teoreticheskaya e`lektrohimiya.− L.: Himiya, 1974.− 568 s. [in Russian]
Miomandr F., Sadki S., Odeber P., Mealle-Reno R. E`lektrohimiya.− M.: Tehnosfera, 2008. − 360 s. [in Russian]
Stromberg A. G., Semchenko D. P. Fizicheskaya himiya. − M.: Vy'sshaya shkola, 2009. − 528 s. [in Russian]
Kumok V. N.− Jurnal fizich. himii. − 1963. − T. 37, № 3. − S. 658 − 661. [in Russian]
Korenman I. M. Analiticheskaya himiya maly'h koncentraciy.− M.: Himiya, 1967. − 168 s. [in Russian]
Stetsyk V. V. Teoret. i e`ksperim. himiya. − 1980. − T. 16, № 1. − S. 41 − 45. [in Russian]
Stetsyk V. V.− Ukrainskiy himich. jurnal. − 2010. − № 6. − S. 93 − 97.
Glesston S. Vvedenie v e`lektrohimiyu.− M.: Izd-vo inostr. lit., 1951.− 767 s. [in Russian]
Stetsyk V. V.- Izvestiya vuzov. Himiya i him. tehnologiya. - 1984. − Vy'p. 8. - S. 920- 922. [in Russian]
Novy'y spravochnik himika i tehnologa. Himicheskoe ravnovesie. Svoystva rastvorov / pod red. S. A. Simanovoy. − SPb.: ANO NPO “Professional”, 2004. − 998 s. [in Russian]
Volkov A. I., Jarskiy I. M. Bol'shoy himicheskiy spravochnik.− Minsk: Sovremennaya shkola, 2005.− 608 s. [in Russian]
