The search of new luminophores with predetermined physicochemical and chemical properties. ХII. N-Sudstituted polyacrylamide and copolymers N-getarylsudstituted acrylamide, getarylacrylate, acrylamide and acrylic acid

  • Anatoliy P. Shkumat V.N. Karazin Kharkiv National University https://orcid.org/0000-0001-9705-6235
  • V. V. Semenchenko V.N. Karazin Kharkiv National University
Keywords: synthesis, acrylamide, polyacrylamide (PAA), acrylic acid, poliacrylic acid, O-arylakrilates, N-hetarylacrylamides, copolymers, luminophores, IR spectra, absorption and fluorescence spectra

Abstract

New approaches to create derivatives of polyacrylic acid and polyacrylamide were elaborated. Copolymers of acrylamide, acrylic acid, N-getarylsubstituted acrylamide and getarylacrylate having fluorescent properties were synthesized and investigated. The IR, UV-Vis absorption and luminescence spectra were studied.

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References

Shkumat A. P. Sopolimers of acrylamide, N-substituted amids of maleinic acid and adducts of maleic acid - 1,3-diaryl-5-(furyl)-2-pyrazolines. International Conference Chemistry of Nitro-gen Containing Heterocycles (CNCH-2006), Kharkiv, Ukraine, October 2-7, 2006/ Book of Abstracts - P. 214.

Shkumat A.P. Poisk novy'h lyuminoforov s zadanny'mi fiziko-himicheskimi svoystvami. VIII. Vodorastvorimy'e sopolimery' akrilamida i Ν-zamesch'enny'h amidov maleinovoy kisloty' //Vi'stnik Harki'vs'kogo naci'onal'nogo uni'versitetu. 2011. № 976. Hi'mi'ya. Vip. 20(43). - s. 74-83.

Shkumat A.P. Poisk novy'h lyuminoforov s zadanny'mi fiziko-himicheskimi svoystvami. IX. Novy'e vodorastvorimy'e sopolimery' akrilamida // Vi'stnik Harki'vs'kogo naci'onal'nogo uni'versitetu. 2012. № 1026. Hi'mi'ya. Vip. 21(44). - s. 126-133.

Shkumat A. P., Pustovarova YU.YU. Poisk novy'h lyuminoforov s zadanny'mi fiziko-himicheskimi svoystvami. XI. Novy'e sintezy' sopolimerov na osnove poliakrilamida // Vi'st-nik Harki'vs'kogo naci'onal'nogo uni'versitetu. 2014. № 1136. Seri'ya "Hi'mi'ya". Vip. 24 (47) - c. 89-100.

Abramova L.I. Poliakrilamid // L.I. Abramova, E.P. Bayburdov - M.: Himiya, 1992. - 192s.

Kurenkov V.F. Vodorastvorimy'e polimery' akrilamida // V.F. Kurenkov // Sorosovskiy obra-zovatel'ny'y jurnal. - 1997. - №5, S 48-53.

Polyacrylamide in Agriculture and Environmental Land Management / R.E. Sojka, D.L. Bjorneberg, J.A. Entry [et al.] // Advances in Agronomy. - 2007. Vol 92, P. 75-162.

Patent 2426545 RF. Sposoby' polucheniya fluorescentny'h proizvodny'h dekstranov. // Shku-rupiy V.A., Luzgina N.G., Troickiy A.V., Gulyaeva E.P. // zayav. 2010116514/15, 26.04.2010.

Human identification analysis to forensic purposes with two mitochondrial markers in polyac-rilamide mini gel / Luciana Caenazzo, Francesca Ceola, Elena Ponzano, Enrico Novelli // Fo-rensic Science International: Genetics Supplement Series. - 2008. Vol. 1, N 1. - P. 266-268.

Acrylamide. TA:IARS Monographs on the evaluation of the carcinogenic risk of chemicals to humans, -2010.- Vol. 60.- R 389-433.

The multiplicative model for cancer risk assessment: applicability to acrylamide / Paulsson B, Granath F, Grawe J, Ehrenberg L, Tornqvist M. // Cancirogenesis.- 2009. -Vol. 22, № 5.- P 917

Relationship between acrylamide reproductive and neurotoxicity in male / Tyl R.W., MarrM.C., Myers C.B., Floss W.P. //Report Toxicol. -2010. - Vol. 14, № 2- P 147-57

Polyacrylamide in Agriculture and Environmental Land Management / R.E. Sojka, D.L. Bjorneberg, J.A. Entry [et al.] // Advances in Agronomy. - 2007. Vol 92, P. 75-162.

Owen A.T. The preparation and ageing of acrylamide acrylate copolymer flocculant solutions // A.T. Owen, P.D. Fawell, J.D. Swift // Inter-national Journal of Mineral Processing. - 2007. - Vol. 84, N 1 - 4. - P. 3 - 14. 608 s.

Smith E. A. Acrylamide and polyacrylamide: a review of production, use, environmental fate and neurotoxicity / E. A. Smith, E. W. Oehme // IARS Monographs on the evaluation of the carcinogenic risk of chemicals to humans. - 2012.- Vol. 100A.- R. 389-433.

Published
2016-12-07
Cited
How to Cite
Shkumat, A. P., & Semenchenko, V. V. (2016). The search of new luminophores with predetermined physicochemical and chemical properties. ХII. N-Sudstituted polyacrylamide and copolymers N-getarylsudstituted acrylamide, getarylacrylate, acrylamide and acrylic acid. Kharkiv University Bulletin. Chemical Series, (27), 60-71. https://doi.org/10.26565/2220-637X-2016-27-08