Acid-base equilibria of sulfonephthalein indicators in micellar solutions of cationic dimeric surfactant

Authors

  • E. V. Pushkarevskaya V.N. Karazin Kharkiv National University
  • S. V. Shehovcov V.N. Karazin Kharkiv National University
  • Natalya A. Vodolazkaya V.N. Karazin Kharkiv National University

DOI:

https://doi.org/10.26565/2220-637X-2013-22-11

Keywords:

acid-base equilibria, sulfonephthalein indicator, micelle of dimeric surfactant, apparent ionization constant, differentiating impact, electrostatic potential

Abstract

The acid-base equilibria of sulfonephthalein indicators in micellar solutions of dimeric bis-quaternary ammonium surfactant (16-4-16) have been investigated. A differentiating impact of dimeric surfactant micelles toward acidic ionization of sulfonephthalein indicators has been found. This effect is more expressed than in usual cationic surfactant micelles. The electrostatic potential value in dimeric surfactant micelles was estimated to be about 120 mV.

References

Gemini surfactants. Synthesis, interfacial and solution-phase behavior, and applications. Sur-factant Science Series / Ed. R. Zana, J. Xia. – Marcel Dekker, 2004. – 331 p.

Menger F.M., Littau C.A. // J. Am. Chem. Soc. – 1993. – Vol. 115. – P. 10083-10090.

Rosen M.J., Tracy D.J. // J. Surf. Deterg. – 1998. – Vol. 1. – P. 547-554.

Shukla D., Tyagi V.K. // J Oleo Sci. – 2006. – Vol. 55. – P. 381-390.

Karpichev E.A. // Voprosy' himii i himicheskoy tehnologii. – 2009. – №5. – S. 140-145.

Bernheim-Groswasser A., Zana R., Talmon Y. // J. Phys. Chem. B. – 2000. – Vol. 104. – P. 4005-4009.

Tehrani-Bagha A.R., Singh R.G., Holmberg K. // J. Colloid Interface Sci. – 2012. – Vol. 376. – P. 112-118.

Mchedlov-Petrosyan N.O. Differencirovanie sily' organicheskih kislot v istinny'h i or-ganizovanny'h rastvorah. - H.: Har'kovskiy nacional'ny'y universitet imeni V.N. Karazina, 2004. – 326 s.

Shahir A.A., Rashidi-Alavijeh M., Javadian S., Kakeman J., Yousefi A. // Fluid Phase Equi-libria. – 2011. – Vol. 305. – P. 219-226.

Downloads

Published

2013-12-20

How to Cite

Acid-base equilibria of sulfonephthalein indicators in micellar solutions of cationic dimeric surfactant. (2013). V. N. Karazin Kharkiv National University Bulletin. Chemical Series, 22, 99-105. https://doi.org/10.26565/2220-637X-2013-22-11

Most read articles by the same author(s)