Determination of interfacial electrostatic potentials of surfactant micelles using acid-base indicators: results and limitations
Abstract
In this paper, the different methods of estimation of the electrostatic potential, Ψ, of surfactant micelles via acid-base indicators are compared. All the methods are based on the determination of the indices of the so-called “apparent” ionization constants, pKaapp. The approach developed in this Laboratory and based on using the indicator N,N /-di-n-octadecylrhodamine is utilized for determination of the Ψ value in the Stern layer of cetyltrimethylammonium-based micelles in the presence of tosylate ion.
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