Effect Of Electrolyte Concentration and Discharge Frequency on Ti-6Al-4V Powder Particle Size Distribution Obtained by ECDM

  • B.A. G'oipov Institute of Ion-Plasma and Laser Technologies named after UA Arifov, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan https://orcid.org/0009-0005-3550-7893
  • A.A. Zaripov Institute of Ion-Plasma and Laser Technologies named after UA Arifov, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan https://orcid.org/0000-0003-4964-1776
  • U.F. Berdiyev Institute of Ion-Plasma and Laser Technologies named after UA Arifov, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan https://orcid.org/0000-0003-2808-0105
  • Sh.Ch. Iskandarov Institute of Ion-Plasma and Laser Technologies named after UA Arifov, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan https://orcid.org/0000-0002-3002-9141
  • T.K. Turdaliev Institute of Ion-Plasma and Laser Technologies named after UA Arifov, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan https://orcid.org/0000-0002-0732-9357
  • S.A. Tulaganov Institute of Ion-Plasma and Laser Technologies named after UA Arifov, Academy of Sciences of the Republic of Uzbekistan, Tashkent, Uzbekistan https://orcid.org/0000-0003-1881-2165
Keywords: Ti-6Al-4V powder, ECDM, Additive manufacturing, NaCl electrolyte, Electrolyte concentration, Particle size distribution, Frequency, Regression analysis

Abstract

This study investigates the distribution of Ti-6Al-4V alloy powder microparticles used in 3D printing under different discharge frequencies and NaCl electrolyte concentrations. This work analyzed the process of obtaining monodisperse Ti-6Al-4V alloy powders using the ECDM method. The results showed that an optimal NaCl electrolyte concentration of 30 g/L ensures stable plasma channel formation and a narrow particle size distribution. Regression analysis and low standard error values (0.00386–0.00834) confirm the process's high controllability. The effect of frequency on particle size was also investigated: at 3.2 kHz, the minimum average particle size of 16.598 µm was recorded, whereas increasing the frequency to 32 kHz increased particle size to 28.063 µm due to thermal accumulation. The results indicate that at both 3.2 kHz and 32 kHz frequencies, 58.24% to 68.89% of the produced powders fall within the 15–55 µm range required for PBF-LB/M technology. These findings demonstrate the suitability of the obtained powders for additive manufacturing technologies.

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References

Kacsó, A. B., & Peter, I. “A Review of Past Research and Some Future Perspectives Regarding Titanium Alloys in Biomedical Applications,” Journal of Functional Biomaterials, 16(4), 144 (2025). https://doi.org/10.3390/jfb16040144

del Bosque, A., Fernández-Arias, P., & Vergara, D. “Titanium Additive Manufacturing with Powder Bed Fusion: A Bibliometric Perspective,” Applied Sciences, 14(22), 10543 (2024). https://doi.org/10.3390/app142210543

Radhika, C., Shanmugam, R., Ramoni, M., & Gnanavel, B. K. “A review on additive manufacturing for aerospace application,” Materials Research Express, 11(2), 022001 (2024). https://doi.org/10.1088/2053-1591/ad21ad

Nyamekye, P., Golroudbary, S. R., Piili, H., Kraslawski, A., & Luukka, P. “Impact of additive manufacturing on titanium supply chain: Case of titanium alloys in automotive and aerospace industries,” Advances in Industrial and Manufacturing Engineering, 6(C), 100112 (2023). https://doi.org/10.1016/j.aime.2023.100112

Zhang, A., Li, Y., Xu, Q., Zhang, B., Qu, P., & Chen, W. “Application Status and Prospect of Titanium Alloys for Pressure-Resistant Structure of Deep-Sea Manned Equipment,” Ship & Boat, 35(06), 81 (2024). https://doi.org/10.19423/j.cnki.31-1561/u.2024.06.007

Iskandarov, S. C., Khudaykulov, I. K., Turdaliev, T. К., Berdiyev, U. F., Tulaganov, S. A., & Kakhramonov, B. R. “Effect of TiO₂ Layer Thickness on Electrode Degradation in Redox Flow Batteries,” East European Journal of Physics, (4), 601-606 (2025). https://doi.org/10.26565/2312-4334-2025-4-63

Wang, L., Zhao, X., Wang, X., Shang, S., Xiu, Z., Xi, Y., et al., “Current Status Review of Corrosion Resistance Applications of Titanium Alloys in the Petroleum Industry,” Coatings, 14(8), 941 (2024). https://doi.org/10.3390/coatings14080941

Kumawat, S., Deshmukh, S.R., & Ghorpade, R.R. “Fabrication of Ti-6Al-4v cellular lattice structure using selective laser melting for orthopedic use: a review,” Materials Today: Proceedings, 113, 166-172 (2024). https://doi.org/10.1016/j.matpr.2023.08.053

Yim, S., Minowa, K., Yamanaka, K., & Chiba, A. “Influence of particle size distribution on the powder bed quality in the powder bed fusion additive manufacturing process,” Journal of Materials Research and Technology, (2025). https://doi.org/10.1016/j.jmrt.2025.06.136

X.X. Yao, and Z. Zhang, “Laser-particle interaction-based heat source model of laser powder bed fusion additive manufacturing,” Opt. Laser Technol. 155, 108402 (2022). https:// doi. org/ 10. 1016/j. optla stec. 2022. 108402

Xue, M., Chen, X., Ji, X., Xie, X., Chao, Q., & Fan, G. “Effect of particle size distribution on the printing quality and tensile properties of Ti-6Al-4V alloy produced by LPBF process,” Metals, 13(3), 604 (2023). https://doi.org/10.3390/met13030604

Soltani-Tehrani, A., Yasin, M. S., Shao, S., Haghshenas, M., & Shamsaei, N. Effects of powder particle size on fatigue performance of laser powder-bed fused Ti-6Al-4V. Procedia Structural Integrity, 38, 84-93 (2022). https://doi.org/10.1016/j.prostr.2022.03.010

Çuvalcı, O., Varol, T., Akçay, S. B., Güler, O., & Çanakçı, A. “Effect of ball mill time and wet pre-milling on the fabrication of Ti powders by recycling Ti machining chips by planetary milling,” Powder Technology, 426, 118637 (2023). https://doi.org/10.1016/j.powtec.2023.118637

Mendez-Lozano, N., Apátiga-Castro, M., Soto, K. M., Manzano-Ramírez, A., Zamora-Antuñano, M., & Gonzalez-Gutierrez, C. “Effect of temperature on crystallite size of hydroxyapatite powders obtained by wet precipitation process,” Journal of Saudi Chemical Society, 26(4), 101513 (2022). https://doi.org/10.1016/j.jscs.2022.101513

Wu, J., Xia, M., Wang, J., Zhao, B., & Ge, C. “Effect of electrode induction melting gas atomization on powder quality: satellite formation mechanism and pressure,” Materials, 16(6), 2499 (2023). https://doi.org/10.3390/ma16062499

Sojoodi, M., Behvar, A., Bajaj, H., Mohajerani, S., Vanaei, S., Taheri Andani, N., et al., “Integration of Circular Economy into Metal Additive Manufacturing: A Review of Ultrasonic Plasma Atomization for Producing Virgin and Recycled NiTi Powder,” Shape Memory and Superelasticity, 1-41 (2025). https://doi.org/10.1007/s40830-025-00589-y

Muthuswamy, P. “Influence of powder characteristics on properties of parts manufactured by metal additive manufacturing,” Lasers in Manufacturing and Materials Processing, 9(3), 312-337 (2022). https://doi.org/10.1007/s40516-022-00177-3

Tammas-Williams, S., Withers, P. J., Todd, I., & Prangnell, P. B. “Porosity regrowth during heat treatment of hot isostatically pressed additively manufactured titanium components,” Scripta Materialia, 122, 72-76 (2016). https://doi.org/10.1016/j.scriptamat.2016.05.002

Ludwig, I., & Kluge, M. “Investigation of an Increased Particle Size Distribution of Ti-6Al-4V Powders Used for Laser-Based Powder Bed Fusion of Metals,” Materials, 17(12), 2942 (2024). https://doi.org/10.3390/ma17122942

Lanzutti, A., & Marin, E. “The challenges and advances in recycling/re-using powder for metal 3D printing: A comprehensive review,” Metals, 14(8), 886 (2024). https://doi.org/10.3390/met14080886

Islam, S. F., Hawkins, S. M., Meyer, J. L., & Sharman, A. R. “Evaluation of different particle size distribution and morphology characterization techniques,” Additive Manufacturing Letters, 3, 100077 (2022). https://doi.org/10.1016/j.addlet.2022.100077

Zhang, S., Guo, K., Qing, Y., & Liu, C. “Research progress on the preparation technology of spherical alloy powders for laser additive manufacturing,” Materials, 18(14), 3385 (2025). https://doi.org/10.3390/ma18143385

Lewis, G. “Aspects of the powder in metal additive manufacturing: a review,” World Journal of Engineering and Technology, 10(2), 363-409 (2022). https://doi.org/10.4236/wjet.2022.102022

Dwivedi, A. P., & Choudhury, S. K. “A Brief Study of the Particulate Matter Emissions During the EDM Process,” in: Green Buildings and Sustainable Engineering, Springer, 2019. https://doi.org/10.1007/978-981-13-1202-1_39

Wang, J., Sánchez, J. A., Wang, Z., Izquierdo, B., & Ayesta, I. “Observations on debris composition and size distribution in WEDM,” Procedia CIRP, 95, 331-336 (2020). https://doi.org/10.1016/j.procir.2020.02.323

Oßwald, K., Woidasky, J., Hoffmann, A. M., & Moser, M. “Suitability of electrical discharge machining debris particles for usage as a powder for selective laser melting: an explorative study,” Progress in Additive Manufacturing, 4(4), 443-449 (2019). https://doi.org/10.1007/s40964-019-00080-y

Rahmati, A., Abdullah, A., & Esmailnia, K. “Metal nanopowder production by cryogenic mechanical collision and pulsed electric discharge methods,” (2021). arXiv preprint arXiv:2112.03055.

Singh, A. K., Mahajan, R., Tiwari, A., Kumar, D., & Ghadai, R. K. “Effect of dielectric on electrical discharge machining: a review,” in: IOP Conference Series: Materials Science and Engineering, 377(1), 012184 (2018). https://doi.org/10.1088/1757-899X/377/1/012184

Murti, V. S. R., & Philip, P. K. “An analysis of the debris in ultrasonic-assisted electrical discharge machining,” Wear, 117(2), 241-250 (1987). https://doi.org/10.1016/0043-1648(87)90258-4

Khanra, A. K., Pathak, L. C., & Godkhindi, M. M. “Microanalysis of debris formed during electrical discharge machining (EDM),” Journal of Materials Science, 42(3), 872-877 (2007). https://doi.org/10.1007/s10853-006-0020-0

Painuly, M., Singh, R. P., & Trehan, R. “Electrochemical machining and allied processes: a comprehensive review,” Journal of Solid State Electrochemistry, 27(12), 3189-3256 (2023). https://doi.org/10.1007/s10008-023-05610-x

Zhang, S., Zhou, J., Hu, G., Wang, L., & Xu, Y. “Process characteristics of electrochemical discharge machining and hybrid methods: a review,” The International Journal of Advanced Manufacturing Technology, 129(5), 1933-1963 (2023). https://doi.org/10.1007/s00170-023-12452-4

Ben Mhahe, F., Zhang, Y., Chen, C., & Umoren, W. I. “Investigation of the influence of different types of electrolytes on the performance of the Electrochemical Discharge Machining process during micromachining of molybdenum,” International Journal of Electrochemical Science, 19(7), (2024). https://doi.org/10.1016/j.ijoes.2024.100647

Rao, P. S., Sharma, V., Kumar, H., & Sushma, S. P. “Electro-Chemical Machining of Titanium Alloys and Various Composites for Efficient Machining Process: A Critical Review,” Fabrication Techniques and Machining Methods of Advanced Composite Materials, 68-81 (2024).

Zhang, L., Kong, L., Lei, W., & Li, Q. “Review of electrochemical discharge machining technology for insulating hard and brittle materials,” Journal of the Brazilian Society of Mechanical Sciences and Engineering, 46(3), 143 (2024). https://doi.org/10.1007/s40430-024-04739-8

Singh, J., Kant, R., Nimesh, A., Katiyar, N., & Bhattacharya, S. “Evaluating electrochemical micromachining capabilities for industrial applications: A review,” Materials and Manufacturing Processes, 39(1), 1-42 (2024). https://doi.org/10.1080/10426914.2023.2219304

Upadhyay, R. K. “Challenges and control strategies for disrupting passive oxide layer formation in electrochemical machining,” Journal of Electrochemical Science and Engineering, 15(5), (2025). http://dx.doi.org/10.5599/jese.2796

Prakash, A., Kumar, A., & Ballav, R. “Process capability of electrochemical discharge machining: a review,” Proceedings of the Institution of Mechanical Engineers, Part L: Journal of Materials: Design and Applications, 238(2), 282-300 (2024). https://doi.org/10.1177/14644207231218386

Published
2026-09-07
Cited
How to Cite
G’oipov, B., Zaripov, A., Berdiyev, U., Iskandarov, S., Turdaliev, T., & Tulaganov, S. (2026). Effect Of Electrolyte Concentration and Discharge Frequency on Ti-6Al-4V Powder Particle Size Distribution Obtained by ECDM. East European Journal of Physics, (3), 378-384. https://doi.org/10.26565/2312-4334-2026-3-33