The optical transparent solid-phase analytical reagents for the photometric and visual-test determination of aluminium
Abstract
The optical transparent solid-phase complexing reagents obtained by the immobilization of metall indicators eriochrome cyanine R, pyrocatechol violet and alizarin red S in gelatin layers of commercial photographic films are recommended for the photometric and visual-test determination of Al(III). The optimal conditions for reagent and metal complexes immobilization were selected, the composition of the products of heterophase reactions was estimated, and their stability were evaluated. The metrological characteristics for photometric and visual determination with the use of recommended solid-phase reagents were determined, the accuracy of the determinations was confirmed by the independent methods.
Downloads
References
Zolotov YU.A.Sorbcionnoe koncentrirovanie mikrokomponentov iz rastvorov: primenenie v neorganicheskom analize / YU.A. Zolotov, G.I. Cizin, S.G. Dmitrienko, E.I. Morosanova. – M.: Nauka, 2007. – 320 s. [in Russian]
Zolotov YU.A. Khimicheskie test-metody analiza. / YU.A Zolotov, V.M. Ivanov, V.G. Amelin – M.: Izd. «Editorial URSS», 2002. – 302 s. [in Russian]
Voda pitna. Normativni' dokumenti: dovi'dnik u 2 t. Tom 1. Za red. I'vanova V.I'.- L'vi'v: NTC «Leonorm-standart», 2001. – 260 s. [in Ukrainian]
Umland F. Theorle und Praktische Anwendung von Komplexbildnern / F. Umland, A. Yanssen, D. Thierig, G. Wünsch. – Frankfurt: Akademische Verlagsgesellschaft, 1971.
Kul'skiy L.A. Spravochnik po svoystvam, metodam analiza i ochistke vody'. CHast' 1. / L.A. Kul'skiy, I.T. Goronovskiy, A.M. Koganovskiy, M.A. SHevchenko. - Kiev: Naukova dumka, 1980. – 680 s. [in Russian]
Fomin G.S. Voda. Kontrol' himicheskoy, bakterial'noy i radiacionnoy bezopasnosti po mejdu-narodny'm standartam. E`nciklopedicheskiy spravochnik / G.S. Fomin. - M.: Gosstandart Ros-sii, 1995. – 618 s. [in Russian]
Ivanov V.M. Pirokatehinovy'y fioletovy'y v spektrofotometricheskih i novy'h opticheskih me-todah / V.M. Ivanov, G.A. Kochelaeva // Uspehi himii. – 2006 – Т.75, №3 – S. 283-295. [in Russian]
Lur'e YU.YU. Analiticheskaya himiya promy'shlenny'h stochny'h vod / YU.YU. Lur'e. - M.: Himiya, 1984. – 448 s. [in Russian]
Unificirovanny'e metody' issledovaniya kachestva vod. CHast' 1. Metody' himicheskogo analiza vod. Tom 1. Osnovny'e metody'. - Moskva, 1987. – 592 s. [in Russian]
Ostrovskaya V.M. Voda. Indikatorny'e sistemy'. / Ostrovskaya V.M., Zaporojec O.A., Bud-nikov G.K., CHernavskaya N.M. - M.: FGUP VTII. – M.: FGUP VTII, 2002. – 226 s. [in Rus-sian]
Amelin V.G. Test-metod analiza s primeneniem immobilizovanny'h na bumage associatov azoproizvodny'h pirokatehina, trioksifluoronov s cetilpiridiniem i ih helatov s ionami metallov / V.G. Amelin, V.M. Ivanov // Jurn. analit. himii. – 2000. – Т. 55, №4. – S. 411–418. [in Rus-sian]
Nadjafova O.YU. Indikatornaya bumaga dlya test-opredeleniya alyuminiya v rastvorah / O.YU. Nadjafova, S.V. Lagodzinskaya, V.V. Suhan // Jurn. analit. himii. – 2001. –Т. 56, №2. – S. 201–205. [in Russian]
Ostrovskaya V.M. Opredelenie alyuminiya v prirodny'h vodah test-polosami na osnove alyu-minona / V.M. Ostrovskaya, E.A. Reshetnyak, N.N. Nemec, V.N. SHevchenko // Metody' i ob`ekty' himicheskogo analiza. – 2009. – Т. 4, №1. – S. 85-91. [in Russian]
Amelin V.G. Osobennosti test-reakciy ionov metallov s hromazurolom S, immobilizovanny'm na tonkosloyny'h matricah / V.G. Amelin, O.B. CHernova // Jurn. analit. himii. – 2008. – Т. 63, №8 – S. 873–879. [in Russian]
Amelin V.G. Fenolkarbonovy'e kisloty' trifenilmetanovogo ryada, immobilizovanny'e na tkanyah iz iskusstvenny'h i natural'ny'h volokon, dlya test-opredeleniya alyuminiya, berilliya i kationny'h PAV / V.G. Amelin, O.B. Gan'kova // Jurn. analit. himii. – 2007. – Т. 62, №3 – S. 318–323. [in Russian]
Amelin V.G. Tverdofaznaya fluorescenciya v himicheskih test-metodah analiza, osnovanny'h na principah planarnoy hromatografii. / V.G. Amelin, N.S. Aleshin // Jurn. analit. himii. – 2009. – T. 64, №1. – S. 1217-1220. [in Russian]
CHernova R.K. Analiticheskie vozmojnosti kserogeley na osnove opoki i silikatnogo kleya s immobilizovanny'm hromazurolom S / R.K. CHernova, L.M. Kozlova, I.V. My'znikova, YU.G. CHudnova // Jurn. analit. himii. – 2004– T.59, №5 – S. 475-479. [in Russian]
Ershova N.I. Application of chromaticity characteristics for direct determination of trace alu-minum with Eriochrome cyanine R by diffuse reflection spectroscopy / N.I. Ershova, V.M. Ivanov // Anal. Chim. Acta. – 2000 – V. 408. – P. 145.
Ivanov V.M. Opredelenie alyuminiya i berilliya metodom spektroskopii diffuznogo otrajeniya s ispol'zovaniem cvetometricheskih funkciy. / V.M. Ivanov, N.I. Ershova // Jurn. analit. himii. – 2001 – T. 56, №12. – S. 1257-1262. [in Russian]
Kochelaeva G.A. Pirokatehinovy'y fioletovy'y v novy'h opticheskih metodah opredeleniya alyuminiya / G.A. Kochelaeva, V.M. Ivanov, E.N. Simonova // Jurn. analit. himii. – 2008. –T. 63, №4. – S. 376-382. [in Russian]
Reshetnyak E.A. Protoliticheskie i kompleksoobrazuyusch'ie svoystva indikatorov v srede je-latinovogo gelya / E.A. Reshetnyak, N.A. Nikitina, L.P. Loginova, N.O. Mchedlov-Petrosyan, N.V. Svetlova // Vestn. Har'k. nac. un-ta. Himiya. – 2005. –Vy'p. 13(36), № 669. – C. 67-82. [in Russian]
Kuznecov V.V. Analiticheskie reakcii kompleksoobrazovaniya organicheskih reagentov s ionami metallov v otverjdennom jelatinovom gele / V.V. Kuznecov, S.V. SHeremet'ev // Jurn. analit. himii. – 2009 – T. 64, №9. – S. 910-919. [in Russian]
Reshetnyak E.A. Opticheskiy sensor na osnove otverjdennogo jelatinovogo gelya dlya fotometricheskogo opredeleniya sul'fatov v vodny'h sredah / E.A. Reshetnyak, V.E. Asmolov, N.N. Nemec, N.A. Nikitina // Vestn. Har'k. nac. un-ta. Himiya. – 2010. – Vy'p. 18(41), № 895 – S. 74-81. [in Russian]
Reshetnyak E.A. Photometric determination of aqueous cobalt(II), nickel(II), copper(II) and iron(III) with 1- nitroso-2-naphtol-3,6-disulfonic acid disodium salt in gelatin films / E.A. Re-shetnyak, N.V. Ivchenko, N.A Nikitina // Cent. Eur. J. Chem. 2012 – V. 10, №5. – P. 1617-1623.
Djeyms T. Teoriya fotograficheskogo processa / T. Djeyms. – Leningrad: Himiya, 1980. – 672 s. [in Russian]
Tihonov V.N. Analiticheskaya himiya alyuminiya / V.N. Tihonov. - M.: Nauka, 1971. - 268 s. [in Russian]
Savvin S.B. Poverkhnostno-aktivnyye veshchestva / S.B. Savvin, R.K. Chernova, S.N. Shtykov. – M.: Nauka, 1991. – 251 s. [in Russian]
Hulaniсki L. Complexometric indicators: characteristics and application / L.Hulaniсki, Glab S., Ackermann G. // Purе & Appl. Chem. – 1983, V. 7, №55. – P. 1137-1230.
Compendium of analytical nomenclature, 3rd edition, edited by J. Inczedy, T. Lengyel, A.M. Ure. – Blackwell Scientfic Publications, 1998.
Ostrovskaya V.M. Test-metod opredeleniya summy' metallov reaktivnoy indikatornoy buma-goy i ego metrologicheskie harakteristiki / V.M. Ostrovskaya, E.A. Reshetnyak, N.A. Nikit-ina, A.V. Panteleymonov, YU.V. Holin // Jurn. analit. him. – 2004. – T. 59, №10. – S. 1101-1108. [in Russian]
GOST 18165-81. Voda pit'evaya. Metody' opredeleniya massovoy koncentracii alyuminiya. - M.: Izdatel'stvo standartov, 1990. - 7 s. [in Russian]
