Phase equilibrium in systems poly-N-vinylpyrrolidone – inorganic salts – water

  • Galyna D. Yukhno V.N. Karazin Kharkiv National University
  • Alla P. Krasnopyorova V.N. Karazin Kharkiv National University
  • V. D. Trifonov V.N. Karazin Kharkiv National University
Keywords: extraction, heterogeneous system, athermal effect binodal, polyvinylpyrrolidone, structure factor, phase diagram

Abstract

The phase equilibria in aqueous two-phase systems based on poly-N-vinylpyrrolidone and some inorganic salts (sodium, magnesium and ammonium sulphate) has been examined in order to select the optimal conditions for obtaining heterogeneous systems for efficient extraction systems for the isolation and separation of metals. Using data on the density of the phases and binodals compositions of coexisting phases in the polyvinylpyrrolidone – salt – water has been calculated.

Downloads

Download data is not yet available.

References

Kirsh Yu.E`. Poli-N-vinilpirrolidon i drugie poli-N-vinilamidy' / Yu.E`. Kirsh. – M.: Nauka, 1998. – 252 s. [in Russian]

Sidel'kovskaya F.P. Himiya N-vinilpirrolidona i ego polimerov / F.P. Sidel'kovskaya. – M.: Nauka, 1970. – 150 s. [in Russian]

Nikolaev A.F. Vodorastvorimy'e polimery' / A.F. Nikolaev, G.I. Ohrimenko. – L.: Himiya, 1979. – 144 s. [in Russian]

Bekturov E.A. Molekulyarny'e kompleksy' polimerov / E.A. Bekturov, R.E`. Hamzamulina, Z.H. Bakauova. – Alma-Ata: Nauka, 1988. – 176 s. [in Russian]

Ostroushko A.A. Sistema geptamolibdat ammoniya-polivinilpirrolidon-voda / A.A. Ostrou-shko, M.YU. Sennikov // Jurn. neorgn. himii. – 2003. – T.48, №4. – S. 655-660. [in Russian]

Al'berston P.O. Razdelenie kletochny'h chastic i makromolekul / P.O. Al'berston. – M.: Mir, 1985. – 150 c. [in Russian]

Voros N. Liquid-liquid Phase Equilibria of Aqueous 2-Phase Systems Containing Salts And Polyethylene Glycol / N. Voros, P. Proust, A. Fredenslund // Fluid Phase Equilibria. – 1993. – Vol.90. – P. 333-354.

Dvuhfazny'e vodny'e sistemy' na osnove polie`tilenglikolya i neorganicheskih soley / T.I. Ni-fant'eva, V. Matoushova, Z. Adamcova, V.M. Shkinev // Vy'sokomolek. soed. A. – 1989. – T.31, №10. – S. 2131-2135. [in Russian]

Opisanie raspredeleniya neorganicheskih soley v rasslaivayusch'ihsya sistemah rastvor e`lektrolita polie`tilenglikol' / V.V Sergievskiy, J.E Djakupova, V.M. SHkinev, B.YA Spiva-kov // Jurn. obsch'. himii. – 1994. – T.64, №1. – S. 23-25. [in Russian]

Rozen A.M. E`kstrakciya v sistemah s dvumya nesmeshivayusch'imisya vodny'mi fazami na osnove polie`tilenglikolya i soli – fazoobrazovatelya kak primer ravnovesiy s dissociaciey v obeih fazah / A.M Rozen, Z.I. Nikolotova, N.A. Kartasheva // Radiohimiya. – 1993. – T.35, №6. – S. 49-62. [in Russian]

Rozen A.M. Voprosy' fazoobrazovaniya pri e`kstrakcii metallov v sistemah polie`tilenglikol' – neorganicheskaya sol' – voda. 1. Izbranny'e aniony', sposobstvuyusch'ie fazaobrazovaniyu / A.M. Rozen, A.M. Safiulina, V.M. SHkinev // Radiohimiya. – 2001. – T.43, №6. – S. 490-493. [in Russian]

Kostromina N. A. Himiya koordinacionny'h soedineniy: uchebnik dlya VUZov / N.A. Kos-tromina. V.N Kumok, N.A Skorik. – M.: Vy'sshaya shkola, 1990. – 432 s. [in Russian]

Voyuckiy S.S. Kurs kolloidnoy himii / S.S Voyuckiy. – M.: Himiya, 1975. – 512 s. [in Russ-ian]

Alimarin I.P. Demonstracionny'y e`ksperiment po obsch'emu kursu analiticheskoy himii / I.P. Alimarin, V.I. Fadeeva, E.N. Dorohova. – M.: Himiya, 1974. – 288 c. [in Russian]

Krestov G.A. Termodinamika ionny'h processov v rastvorah / G.A. Krestov. – L.: Himiya, 1984. – 272 s. [in Russian]

Ueberreiter K. Change of water structure by solvents and polymers / K. Ueberreiter // Colloid Polymer Sci. – 1982. – Vol.260, №1. – P. 37-45.

Thermodynamic properties of aqueous solutions of macromolecular compounds. I. Solutions of polyethylene glycol and polyacrylamide / A.A. Masimov, B.Yu. Zaslavsky, A.A. Gasanov, S.V. Rogozhin // J. Chromatogr. – 1984. – Vol.284, №2. – P. 337-348.

Clark A. H. Direct analysis of experimental tie line data (two polymer–one solvent systems) using Flory–Huggins theory / A. H. Clark // Carbohydrate Polymers. – 2000. – V. 42. – P. 337–351.

Foroutan M. Quaternary (liquid+liquid) equilibria of aqueous two–phase polyethylene glycol, poly-N-vinylcaprolactam and KH2PO4 system: Experimental and generalized Flory–Huggins Theory / M. Foroutan, M. Zarrabi // J. Chem. Therm. – 2008. – V. 40. – P. 935-941.

Bekturov E.A. Sinteticheskie vodorastvorimy'e polimery' v rastvorah / E.A. Bekturov, Z.H. Bakauova. – Alma-Ata: Nauka, 1981. – 149 s. [in Russian]

Voprosy' fazoobrazovaniya pri e`kstrakcii metallov v sistemah polie`tilenglikol' – neorgani-cheskaya sol' – voda. 2. Binarnaya sistema polie`tilenglikol' – voda / A.M. Rozen, A.M. Safiu-lina, V.M. Shkinev, V.P. Nikolaev // Radiohimiya. – 2002. – T.44, №3. – S. 245-247. [in Russian]

Published
2014-09-03
Cited
How to Cite
Yukhno, G. D., Krasnopyorova, A. P., & Trifonov, V. D. (2014). Phase equilibrium in systems poly-N-vinylpyrrolidone – inorganic salts – water. Kharkiv University Bulletin. Chemical Series, (23), 81-88. https://doi.org/10.26565/2220-637X-2014-23-10