The refinement of limiting molar conductivities of weak acids and bases
DOI:
https://doi.org/10.26565/2220-637X-2013-22-18Keywords:
molar conductivity of acids, molar conductivity of bases, additivity of conductivity, infinitely diluted electrolytesAbstract
The paper emphasizes that the values of limiting molar conductivity of fairly weak acids and bases mentioned in the contemporary research papers do not comply with the action mass law; they are conventional values representing sums of limiting mobilities of the cations and anions rather than real limiting molar conductivities. Taking into account the mole fractions of different electro-lyte forms while C→0, found with strict application of the action mass law, the method of the re-finement of the values of limiting molar conductivities of weak acids and bases has been proposed.
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